4-Benzoyloxy-TEMPO 4-苄酰氧基-四甲基哌啶氧自由基

CAS 3225-26-1 MFCD00075563

化学结构图

3225-26-1
SMILES: CC1(C)CC(OC(=O)c2ccccc2)CC(C)(C)N1[O]

化学属性

Mol. FormulaC16H22NO3
Mol. Weight276.35
Melting Point99-101 °C

别名和识别编码

Chemical Name4-Hydroxy-TEMPO Benzoate, Free Radical
Synonym 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {} {} {} {} {} {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {} {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {} {} {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {} {} {} {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {} {} {} {} {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {} {} {} {} {} {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00075563
PubChem Substance ID2847363
Beilstein Registry Number1431263
CAS Number3225-26-1
Reaxys-RN1431263
Chemical Name Translation4-苄酰氧基-四甲基哌啶氧自由基
LabNetwork Molecule IDLN01742640
InChIInChI=1S/C16H22NO3/c1-15(2)10-13(11-16(3,4)17(15)19)20-14(18)12-8-6-5-7-9-12/h5-9,13H,10-11H2,1-4H3
Canonical SMILESCC1(CC(OC(C2=CC=CC=C2)=O)CC(C)([N+]1[O-])C)C
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分类

  • {SNA} Chemical Synthesis, Electron Spin Resonance (ESR/EPR) Spectroscopy,
  • {SNA} Che
  • Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Electron Spin Resonance (ESR/EPR) Spectroscopy, Radical Chemistry, Spectroscopy, Spin Labels, Stable Radicals, Synthetic Reagents, TEMPO Derivatives
  • {SA} Chemical Synthesis, Radical Chemistry, Stable Radicals, Synthetic Reagents, TEMPO Derivatives
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Electron Spin Resonance (ESR/EPR) Spectroscopy, Radical Chemistry, Spectroscopy, Spin Labels, Stable Radicals, Synthetic Reagents,

相关文献及参考

  • 1. J. Org. Chem. 55 , 462, (1990)
  • Beil. 21 ,1,166
  • RegBook 1 (2), 1901:E / Structure Index 1 , 304:A:4

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P301+P317
  • P305+P351+P338
  • P319
  • P330 Rinse mouth. 漱口
  • P337+P317
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H320 Causes eye irritation 刺激眼睛
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官

其他信息

  • TCI Shanghai:4-苯甲酰氧基-2,2,6,6-四甲基哌啶-1-氧基自由基[氧化反应的催化剂] 4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate Free Radical [Catalyst for Oxidation],>;97.0%(GC)(3225-26-1)
  • Sigma Aldrich:3225-26-1(sigmaaldrich)
  • MOL 文件:3225-26-1.mol
  • 4-苄酰氧基-四甲基哌啶氧自由基价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0878 4-羟基-2,2,6,6-四甲基哌啶1-氧基苯甲酸盐自由基[氧化反应的催化剂] 4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate Free Radical [Catalyst for Oxidation] 5G 2060元 2014/06/02 H0878 4-羟基-2,2,6,6-四甲基哌啶1-氧基苯甲酸盐自由基[氧化反应的催化剂] 4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate Free Radical [Catalyst for Oxidation] 1G 675元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Spectroscopy - Analytical Reagents
  4. Electron Spin Resonance (ESR/EPR) Spectroscopy - Spectroscopy
  5. Spin Labels - Electron Spin Resonance (ESR/EPR) Spectroscopy
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals - Radical Chemistry
  5. TEMPO Derivatives - Stable Radicals
  1. Analytical & Chromatography 分析化学与色谱
  2. ESR Spectrometry
  1. Functional Group 官能团索引
  2. hydroxylamine

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