1-Azido-4-fluorobenzene 1-Azido-4-fluorobenzene

CAS 3296-02-4 MFCD11207332

化学结构图

3296-02-4
SMILES: [N-]=[N+]=Nc1ccc(F)cc1

化学属性

Mol. FormulaC6H4FN3
Mol. Weight137.11

别名和识别编码

Chemical Namesolution ~0.5 M in tert-butyl methyl ether, >=95.0% (HPLC)
Synonym 4-Fluorophenyl azide solution
MDL NumberMFCD11207332
Beilstein Registry Number1939307
CAS Number3296-02-4
PubChem Substance ID10887974
Chemical Name Translation1-Azido-4-fluorobenzene
InChIInChI=1S/C6H4FN3/c7-5-1-3-6(4-2-5)9-10-8/h1-4H
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分类

  • Aromatic Azides, Azides, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Hu, M., et al., In situ “click” assembly of small molecule matrix metalloprotease inhibitors containing zinc-chelating groups Org. Lett. 10(2) , 5529-5531, (2008) 摘要
  • Smalley, R. K. and Suschitzky, H., Decomposition of halogen-substituted phenyl azides J. Chem. Soc. , 5922-5925, (1964)

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P235 Keep cool. 保持凉爽。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P370+P380+P375
  • P378 Use … for extinction. 使用...灭火。
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P410 Protect from sunlight. 防止阳光照射。
  • P411 Store at temperatures not exceeding … oC/…oF. 储存在温度不超过…oC /…oF。
  • P420 Store away from other materials. 远离其他材料。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H241 Heating may cause a fire or explosion 加热可能会引起火灾或爆炸
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Hazard Codes F,T
Risk Statements
  • R11 Highly flammable 非常易燃
  • R48/23/24/25
  • R38 Irritating to skin 刺激皮肤

系列性分类


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