Lithium dimethylamide 二甲基胺锂
CAS 3585-33-9 MFCD00008295
化学结构图
SMILES: [Li]N(C)C
化学属性
| Mol. Formula | C2H6LiN |
|---|---|
| Mol. Weight | 51.02 |
| TSCA | No |
| Melting Point | dec. |
| Density | 0.68 g/mL at 25 °C |
| Boiling Point | 68-70 °C |
别名和识别编码
| Chemical Name | Lithium dimethylamide |
|---|---|
| MDL Number | MFCD00008295 |
| CAS Number | 3585-33-9 |
| PubChem Substance ID | 5152226 |
| Beilstein Registry Number | 3618233 |
| EC Number | 222-714-3 |
| Synonym | 二甲基胺锂 制备 |
| Chemical Name Translation | 二甲基胺锂 |
| InChIKey | ZXSRVMKDJDTZSW-UHFFFAOYSA-N |
| InChI | InChI=1S/C2H6N.Li/c1-3-2;/h1-2H3;/q-1;+1 |
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分类
- {SNA} Chemical Synthesis, Organic Bases, Synthetic Reagents
安全信息
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P222 Do not allow contact with air. 不要与空气接触。
- P231+P232
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P302+P334
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P402+P404
- P405 Store locked up. 上锁保管。
- P422 Store contents under… 存储目录在…之下。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- R48/20
- R14 Reacts violently with water 遇水会猛烈反应
- R17 Spontaneously flammable in air 在空气中能够自燃
- R34 Causes burns 会导致灼伤
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R51/53
- R11 Highly flammable 非常易燃
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
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