1-Azido-3-methoxybenzene 3-Azidoanisole
CAS 3866-16-8 MFCD17677175
化学结构图
SMILES: COc1cccc(N=[N+]=[N-])c1
化学属性
| Mol. Weight | 149.15 |
|---|---|
| Mol. Formula | C7H7N3O |
别名和识别编码
| Synonym | 1-Azido-3-methoxybenzene solution 1-Azido-3-methoxybenzene solution 3-Methoxyphenyl azide solution 3-Methoxyphenyl azide solution |
|---|---|
| MDL Number | MFCD17677175 |
| Beilstein Registry Number | 2090296 |
| CAS Number | 3866-16-8 |
| Chemical Name | solution 0.5 M in tert-butyl methyl ether, >=97% (HPLC) |
| PubChem Substance ID | 542844 |
| Chemical Name Translation | 3-Azidoanisole |
| LabNetwork Molecule ID | LN04675829 |
| InChI | InChI=1S/C7H7N3O/c1-11-7-4-2-3-6(5-7)9-10-8/h2-5H,1H3 |
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分类
- Aromatic Azides, Azides, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
相关文献及参考
- Leffler, J.E. and Temple, R.D. , The staudinger reaction between triarylphosphines and azides. A study of the mechanism. J. Am. Chem. Soc. 89 , 5235-5246, (1967)
安全信息
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
- P234 Keep only in original container. 只保留在原来的容器中。
- P235 Keep cool. 保持凉爽。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P370+P378
- P370+P380+P375
- P378 Use … for extinction. 使用...灭火。
- P403 Store in a well-ventilated place. 储存在通风良好的地方。
- P403+P233
- P403+P235
- P405 Store locked up. 上锁保管。
- P410 Protect from sunlight. 防止阳光照射。
- P411 Store at temperatures not exceeding … oC/…oF. 储存在温度不超过…oC /…oF。
- P420 Store away from other materials. 远离其他材料。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H241 Heating may cause a fire or explosion 加热可能会引起火灾或爆炸
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- R11 Highly flammable 非常易燃
- R48/23/24/25
- R38 Irritating to skin 刺激皮肤
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
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