Diphenyl phosphite 亚磷酸二苯酯

CAS 4712-55-4 MFCD00044497

化学结构图

4712-55-4
SMILES: O=[PH](Oc1ccccc1)Oc1ccccc1

化学属性

Mol. FormulaC12H11O3P
Mol. Weight234.19
Refractive index1.5560 to 1.5620
Boiling Point218-219 °C at 26 mmHg
Density1.223 g/mL at 25 °C(lit.)
Melting Point12 °C
Vapor Density8.1 (vs air)
Vapor Pressure5 mmHg ( 140 °C)
Flash Point186°C(lit.)

别名和识别编码

Chemical NameDiphenyl phosphite, 80%, contains 5% phenol
Synonym Diphenyl phosphite {LY} Diphenyl phosphite diphenyl phosphite {} {LY} Diphenyl phosphite {} {} {LY} Diphenyl phosphite {} {} {} {LY} Diphenyl phosphite {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphen
CAS Number4712-55-4
PubChem Substance ID6327546
EC Number225-202-8
Beilstein Registry Number2051909
MDL NumberMFCD00044497
Reaxys-RN2051909
Chemical Name Translation亚磷酸二苯酯
LabNetwork Molecule IDLN00242598
InChIInChI=1S/C12H10O3P/c13-16(14-11-7-3-1-4-8-11)15-12-9-5-2-6-10-12/h1-10H/q+1
Canonical SMILESO=P(OC1=CC=CC=C1)OC2=CC=CC=C2
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds

相关文献及参考

  • 1. A. K. Kyazim-zade and A. A. Gadirov, Synthesis of N-benzylarylamine derivatives and diphenyl esters of a-aminomethanephosphonic acids and examination of their antioxidant properties Petrol. Chem. 51 , 465-468, (2011)
  • 2. C. Venkateswarlu, et al., Synthesis and spectral characterization of some new dibutyl/diphenyl a-aminophosphonates by one-pot three-component Kabachnik-Fields reaction Org. Chem.: An Indian Journal 7 , 320-324, (2011)
  • 3. K. Ando and T. Egami, Facile synthesis of α-amino phosphonates in water by Kabachnik-Fields reaction using magnesium dodecyl sulfate Heteroatom Chem. 22 , 358-362, (2011)
  • 4. M. Rueping, et al., Photoredox catalyzed C-P bond forming reactions-visible light mediated oxidative phosphonylations of amines Chem. Commun. 47 , 8679-8681, (2011)
  • 5. M. T. Barros and A. M. F. Phillips, Organocatalyzed Synthesis of Tertiary a-Hydroxyphosphonates by a Highly Regioselective Modified Pudovik Reaction Eur. J. Org. Chem. 2011 , 4028-4036, (2011)
  • 6. D. Yang, et al., Copper/DIPEA-Catalyzed, Aldehyde-Induced Tandem Decarboxylation-Coupling of Natural a-Amino Acids and Phosphites or Secondary Phosphine Oxides J. Org. Chem. 76 , 6426-6431, (2011)
  • Aldrich MSDS 1 , 830:A / Corp MSDS 1 (1), 1464:D / FT-IR 1 (2), 551:B / FT-IR 2 (2), 3345:A / FT-NMR 1 (2), 1683:A / IR-Spectra (2), 1034:B / IR-Spectra (3), 1187:D / NMR-Reference 2 (2), 888:A / RegBook 1 (2), 2285:B / Structure Index 1 , 357:C:7 / Vapor Phase 3 , 1440:B
  • Beil. 6 ,IV,703
  • Fieser 4 ,210
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Land

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P317
  • P333+P317
  • P337+P317
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 3265
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
Risk Statements
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Packing GroupIII
Hazard Class8
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 蒸气压:5 mm Hg ( 140 °C)
  • 图谱信息:磷酸二苯酯(4712-55-4)质谱(MS) 磷酸二苯酯(4712-55-4)Raman光谱 磷酸二苯酯(4712-55-4)核磁图( 13 CNMR) 磷酸二苯酯(4712-55-4)核磁图( 1 HNMR) 磷酸二苯酯(4712-55-4)红外图谱(IR1)
  • F:21
  • Sigma Aldrich:4712-55-4(sigmaaldrich)
  • 蒸气密度:8.1 (vs air)
  • MOL 文件:4712-55-4.mol
  • Acros Organics:亚磷酸二苯酯 Diphenyl phosphite, contains varying amounts of phenol and (C6H5)3P(4712-55-4)
  • TCI Shanghai:亚磷酸二苯酯 Diphenyl Phosphite (contains 5% Phenol at maximum)(4712-55-4)
  • 磷酸二苯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0907 亚磷酸二苯酯(最多含5%的苯酚) Diphenyl Phosphite (contains 5% Phenol at maximum) 25G 142元 2014/06/02 D0907 亚磷酸二苯酯(最多含5%的苯酚) Diphenyl Phosphite (contains 5% Phenol at maximum) 500G 658元 2010/06/21 117390050 磷酸二苯酯 Diphenyl phosphite , contains varying amounts of phenol and (C6H5O)3P 5 GR 297元
  • 磷酸二苯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D0907 亚磷酸二苯酯(最多含5%的苯酚) Diphenyl Phosphite (contains 5% Phenol at maximum) 25G 139元 2011/04/16 D0907 亚磷酸二苯酯(最多含5%的苯酚) Diphenyl Phosphite (contains 5% Phenol at maximum) 500G 655元 2010/06/21 117390050 磷酸二苯酯 Diphenyl phosphite , contains varying amounts of phenol and (C6H5O)3P 5 GR 297元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Organic Phosphates/Phosphites - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonates/Phosphinates - Phosphorus Compounds

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