Morpholineborane 硼烷吗啉络合物

CAS 4856-95-5 MFCD00066736

化学结构图

4856-95-5
SMILES: C1COCCN1.[B]

化学属性

Mol. FormulaC4H12BNO
Mol. Weight101
Density1.422
Melting Point97-99
TSCAYes
SolubilityMAY DECOMPOSE
Stability对湿度敏感

别名和识别编码

Chemical NameMorpholineborane
CAS Number4856-95-5
EC Number225-450-7
Beilstein Registry Number2384789
MDL NumberMFCD00066736
Synonym MORPHOLINE BORANE borane,compd.withmorpholine morpholine,compd.withborane(1:1) BORANE-MORPHOLINE DIETHYLENE IMIDOXIDE BORANE morpholineborane,mpb morpholineborohydride 硼烷吗啉络合物 BORANE-MORPHOLINE COMPLEX Morpholine, boron complex 吗啉硼烷 NSC 93813 Trihydro(morpholine-N4)boron 吗啉硼烷 Boranemorpholinecomplex,97% TETRAHYDRO-P-OXAZINE BORANE Morpholine borane Borane-morpholine complex; Morpholine-borane Boron, trihydro(morpholine-.kappa.N4)-, (T-4)- DIETHYLENE OXIMIDE BORANE Borane, compound with morpholine
PubChem Substance ID6327109
Reaxys-RN13732283
Chemical Name Translation硼烷吗啉络合物
InChIKeyWILVPUFGQGZGOC-UHFFFAOYSA-N
InChIInChI=1S/C4H9NO.B/c1-3-6-4-2-5-1;/h5H,1-4H2;
LabNetwork Molecule IDLN00222783
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分类

  • {SNA} Boranes, Chemical Synthesis, Reduction, Synthetic Reagents

产品应用

  • Reactant involved in:Ethanolysis producing a reducing system; Being a reducing agent for synthesis of Rh nanoparticle / carbon nanotube catalysts;Stereoselective and regioselective reduction of steroidal ketones; Methanolic cleavage4

相关文献及参考

  • Treatment with n-BuLi generates the lithium aminoborohydride, a powerful reducing agent similar to LiAH4 in its reducing power, but air-stable and non-pyrophoric: J. Org. Chem., 59, 6378 (1994).
  • Selective reducing agent. Reactivity in carbonyl reductions is increased in acidic media: J. Am. Chem. Soc., 92, 4203 (1970); J. Chem. Soc., Perkin 2, 1948 (1973). For a review of amine boranes as selective reducing and hydroborating agents, see: Org. Prep. Proced. Int., 16, 335 (1984).

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSQD8530000
Packing GroupII
UN Number UN 3263 8/PG 2 2921
Hazard Codes C C;Xi
Hazard statements
  • H228 Flammable solid 易燃固体
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Storage condition 0-10 储存温度2-8°C 0-10°C Refrigerator
Hazard Class8/4.1

其他信息

  • TCI Shanghai:吗啉硼烷 Borane - Morpholine Complex,>;95.0%(T)(4856-95-5)
  • Sigma Aldrich:4856-95-5(sigmaaldrich)
  • 吗啉硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0898 硼烷-吗啉络合物 Borane - Morpholine Complex 5G 235元 2014/06/02 M0898 硼烷-吗啉络合物 Borane - Morpholine Complex 25G 690元 2010/06/21 177290250 吗啉硼烷 Borane-morpholine complex 97% 25 GR 841元
  • Alfa Aesar:吗啉硼烷,97% Borane-morpholine complex, 97%(4856-95-5)
  • 图谱信息:吗啉硼烷(4856-95-5)核磁图( 13 CNMR) 吗啉硼烷(4856-95-5)红外图谱(IR1) 吗啉硼烷(4856-95-5)质谱(MS) 吗啉硼烷(4856-95-5)Raman光谱 吗啉硼烷(4856-95-5)红外图谱(IR2)
  • MSDS 信息:Morpholineborane(4856-95-5).msds
  • Acros Organics:Borane-morpholine complex, 97%(4856-95-5)
  • MOL 文件:4856-95-5.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Morpholines/Thiomorpholines 吗啉/硫吗啉
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物

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