5-Norbornene-2-carboxaldehyde, 95%, mixture of endo and exo 5-降冰片烯-2-甲醛
CAS 5453-80-5 MFCD00167568
化学结构图
SMILES: O=CC1CC2C=CC1C2
化学属性
| Mol. Formula | C8H10O |
|---|---|
| Mol. Weight | 122 |
| Density | 1.03 |
| Refractive index | 1.4860 to 1.4900 |
| Boiling Point | 67-70 |
| Flash Point | 50°C(lit.) |
| TSCA | Yes |
| Solubility | 不溶 |
别名和识别编码
| Chemical Name | 5-Norbornene-2-carboxaldehyde, 95%, mixture of endo and exo |
|---|---|
| CAS Number | 5453-80-5 |
| EC Number | 226-698-9 |
| Beilstein Registry Number | 1363813 |
| MDL Number | MFCD00167568 |
| Synonym | BICYCLO 2.2.1!HEPT-5-ENE-2- & 5-NORBORNENE-2-CARBALDEHYDE 5-NORBORNENE-2-CARBOXALDEHYDE 5-NORBORNENE-2-CARBOXALDEHYDE, ENDO AND EXO AKOS BC-0598 5-Norbornane-2-carboxaldehyde 5-NORBORNENE-2-CARBOXALDEHYDE, ENDO + EXO, 95% 5-NORBORNENE-2-CARBOXALDEHYDE, 95%, MIXT URE OF ISOMERS 5-降冰片烯-2-甲醛, ENDO + EXO 5-降冰片-2-甲醛 5-Formylbicyclo-2-heptene 5-Formylbicyclohept-2-ene 2-Formyl-5-norbornene BICYCLO[2.2.1]-5-HEPTEN-2-YL METHANAL 双环[2.2.1]庚-5-烯-2-甲醛 5-Formyl-2-norbornene. 5-Norbornene-2-carboxaldehyde,endo+exo,95% Bicyclo[2.2.1]hept-5-en-2-aldehyde 5-Norbornene-2-carboxaldehyde, mixture of endo and exo, 90-95% 5-降冰片烯-2-甲醛 5-norbornene-2-carboxaldehyde,mixtureofendoandexo 5-降冰片烯-2-甲醛,内型结构和外型结构 TIMTEC-BB SBB005755 5-降冰烯-2-甲醛 BICYCLO[2.2.1]HEPT-5-ENE-2-CARBALDEHYDE Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXALDEHYDE |
| PubChem Substance ID | 95117 |
| Reaxys-RN | 1363813 |
| Chemical Name Translation | 5-降冰片烯-2-甲醛 |
| InChIKey | AJIBZRIAUXVGQJ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00220733 |
| InChI | InChI=1S/C8H10O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,5-8H,3-4H2 |
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分类
- {SNA} Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Materials Science, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science
- {SNA} Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
- {SNA} Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science, 材料科学
相关文献及参考
- Aldol condensation with formaldehyde, followed by crossed Cannizzaro reduction, gives norbornene-2,2-dimethanol, from can be thermolyzed to vinyl-1,1-dimethanol: Tetrahedron Lett., 3775 (1975). For a review of cycloreversion reactions in organic synthesis, see: Synthesis, 121 (1985).
- Diels-Alder adduct of acrolein and cyclopentadiene. Can be used as protected form of acrolein, from which the double bond may be liberated by cycloreversion, e.g. in a useful synthesis of 2-vinylimidazole: Angew. Chem. Int. Ed., 22, 560 (1983):
- Beilstein: 7,II,125
安全信息
GHS Symbol
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P305+P351+P338
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H226 Flammable liquid and vapour 易燃液体和蒸气
其他信息
- Acros Organics:5-降冰烯-2-甲醛 5-Norbornene-2-carboxaldehyde, mixture of endo and exo, 90-95%(5453-80-5)
- Sigma Aldrich:5453-80-5(sigmaaldrich)
- TCI Shanghai:5-降冰片烯-2-甲醛 5-Norbornene-2-carboxaldehyde,>;95.0%(GC)(5453-80-5)
- MSDS 信息:5-Norbornene-2-carboxaldehyde(5453-80-5).msds
- 5-降冰片烯-2-甲醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0504 5-降冰片烯-2-甲醛 5-Norbornene-2-carboxaldehyde 25ML 597元 2010/06/21 149101000 5-降冰片烯-2-甲醛 5-Norbornene-2-carboxaldehyde 90-95%, mixture of endo and exo 100 GR 2361元 2010/06/21 149100250 5-降冰片烯-2-甲醛 5-Norbornene-2-carboxaldehyde 90-95%, mixture of endo and exo 25 GR 937元
- MOL 文件:5453-80-5.mol
- Alfa Aesar:5-降冰片烯-2-甲醛,endo+exo,95% 5-Norbornene-2-carboxaldehyde, endo + exo, 95%(5453-80-5)
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