3-(Trimethylsilyl)Propynoic Acid 3-(三甲基硅基)丙炔酸

CAS 5683-31-8 MFCD00190216

化学结构图

5683-31-8
SMILES: C[Si](C)(C)C#CC(=O)O

化学属性

Mol. FormulaC6H10O2Si
Mol. Weight142.23
Boiling Point219.1±9.0°C at 760 mmHg
Melting Point47-49°C
Flash Point96°C
TSCANo

别名和识别编码

Chemical Name3-(Trimethylsilyl)Propynoic Acid
MDL NumberMFCD00190216
CAS Number5683-31-8
Synonym 3-(Trimethylsilyl)propiolic acid {LY} 3-(Trimethylsilyl)propiolic acid {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trimethylsilyl)propiolic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID2760863
Beilstein Registry Number1755674
Chemical Name Translation3-(三甲基硅基)丙炔酸
Reaxys-RN1755674
LabNetwork Molecule IDLN00202456
InChIInChI=1S/C6H10O2Si/c1-9(2,3)5-4-6(7)8/h1-3H3,(H,7,8)
Canonical SMILESC[Si](C)(C)C#CC(O)=O
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分类

  • {SA} Building Blocks, C6, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks

产品应用

  • 3-(Trimethylsilyl)propynoic acid may be used in the regioselective preparation of 1,5-trisubstituted 1H-1,2,3-triazoles.

相关文献及参考

  • Beilstein: 4,IV,3970

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Store at room temperature {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under

其他信息

  • TSCA:No
  • MOL 文件:5683-31-8.mol
  • F:1-10
  • Sigma Aldrich:5683-31-8(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Conjugation Chemistry: Azides, Alkynes 共轭化学 (叠氮化物，炔烃等)
  4. Functionalized Alkynes 功能性炔烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  6. C6 - Carboxylic Acids

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