3,3’-Dimethylbenzidine Dihydrochloride 盐酸邻联甲苯胺

CAS 612-82-8 MFCD00012960

化学结构图

612-82-8
SMILES: Cc1cc(-c2ccc(N)c(C)c2)ccc1N.Cl.Cl

化学属性

Mol. FormulaC14H16N2.2HCl
Mol. Weight285
Melting Point>300°
TSCAYes
Density1.422
Stability对空气和光敏感

别名和识别编码

Chemical Name3,3’-Dimethylbenzidine Dihydrochloride
MDL NumberMFCD00012960
CAS Number612-82-8
Synonym 联邻甲苯胺 二盐酸盐 4,4'-BI-O-TOLUIDINE DIHYDROCHLORIDE O-TOLIDINE HYDROCHLORIDE 2,3'-Dimethylbiphenyl-4,4'-diamine dihydrochloride 邻二氨基二甲基联苯盐酸 4,4'-二氨基-3,3'-二甲基联苯盐酸盐 二甲基苯二盐酸盐 邻联甲苯胺盐酸盐 3,3’-dimethyl-benzidindihydrochloride 4,4'-DIAMINO-3,3'-DIMETHYLBIPHENYL DIHYDROCHLORIDE 盐酸邻联甲苯胺 邻联甲苯胺二盐酸盐 O-TOLIDINE DI HCL O-TOLIDINE HYDROCHLORIDE R. G. 4,4'-DIAMINO-3,3'-DIMETHYLBIPHENYL HYDROCHLORIDE 3,3'-DIMETHYLBENZIDENE DIHYDROCHLORIDE 3,3'-DIMETHYL-4,4'-DIPHENYLDIAMINE DIHYDROCHLORIDE 3,3-二甲-[4,4]-二氨基聯苯二鹽酸 盐酸-3,3′-二甲基-4,4′-二氨基联苯 3,3′-Dimethyl-4,4′-diamino biphenyl dihydrochloride 3,3'-DIMETHYLBENZIDINE DIHYDROCHLORIDE 3,3'-DIMETHYLBENZIDINIUM DICHLORIDE 4,4'-bianisidine dihydrochloride 1’-biphenyl)-4,4’-diamine,3,3’-dimethyl-(dihydrochloride 联邻甲苯胺盐酸盐 1’-biphenyl]-4,4’-diamine,3,3’-dimethyl-[dihydrochloride 盐酸-3,3'-二甲基联苯胺 (1,1'-Biphenyl)-4,4'-diamine, 3,3'-dimethyl-, dihydrochloride o-Tolidine dihydrochloride TIMTEC-BB SBB003003 3,3′-二甲基联苯胺盐酸 O-TOLIDINE DIHYDROCHLORIDE 4,4'-Diamino-3,3'-dimethylbiphenyl dihydrochloride o-Tolidine dihydrochloride; 4,4'-Bianisidine dihydrochloride; 4,4'-Diamino-3,3'-dimethylbiphenyl dihydrochloride 2,3’-dimethylbiphenyl-4,4’-diaminedihydrochloride 3,3'-Dimethylbenzidine dihydrochloride 邻甲苯胺二盐酸盐, ACS O,O'-DIAMINO-P,P'-DITOLYL DIHYDROCHLORIDE 4,4'-二氨基-3,3'-二甲基联苯盐酸盐 相关CAS 304671-77-0 3,3'-DIMETHYL-(1,1'-BIPHENYL)-4,4'-DIAMINE DIHYDROCHLORIDE 邻甲苯胺二盐酸盐
PubChem Substance ID108938
Beilstein Registry Number13,257
EC Number210-322-5
Reaxys-RN3713238
Chemical Name Translation盐酸邻联甲苯胺
Wiswesser Line NotationZR B1 DR DZ C1 &GH 2
LabNetwork Molecule IDLN00194713
InChIInChI=1S/C14H16N2.2ClH/c1-9-7-11(3-5-13(9)15)12-4-6-14(16)10(2)8-12;;/h3-8H,15-16H2,1-2H3;2*1H
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分类

  • {SNA} Amine Salts, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 金和水中游离氯的灵敏性比色测定试剂。

相关文献及参考

  • Merck: 14,9514 Beilstein:13,257

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P318
  • P319
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H350 May cause cancer 可能致癌
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word
RTECSDD1226000
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Packing GroupIII
UN Number 1789/3077 3077 UN 3077 9/PG 3 UN3077
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R22 Harmful if swallowed 吞咽有害
  • R51/53
Storage condition 应密封于干燥处保存。 Air & Light Sensitive Air Sensitive
Hazard Codes T,N 9
Hazard Class9
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1820 mg/kg/65W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Skin and Appendages - tumors
REFERENCE :
   JACTDZ Journal of the American College of Toxicology.  (Mary Ann Liebert,
   Inc., 1651 Third Ave., New York, NY 10128)  V.1-12, 1982-1993. Discontinued.
    Volume(issue)/page/year: 10(2),255,1991

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 15288 mg/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   27,801,1989

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 2750 ppm
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,325,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Unreported
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 2750 ppm
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-390,1991

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 14 pph
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,325,1985

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 10 mg/L
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-390,1991

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 20 mg/L
REFERENCE :
   NTPTR* National Toxicology Program Technical Report

其他信息

  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 毒性分级:高毒
  • 敏感性:Air Sensitive
  • color:white to light yellow
  • 用途一:金和水中游离氯的灵敏性比色测定试剂。
  • 图谱信息:盐酸-3,3'-二甲基联苯胺(612-82-8)红外图谱(IR1) 盐酸-3,3'-二甲基联苯胺(612-82-8)红外图谱(IR2)
  • 可燃性危险特性:明火可燃; 受热放出有毒氯化氢和氧化氮气体
  • 外观性质:浅褐色至灰褐色结晶粉末，能溶于水和稀盐酸。
  • F:3-8-9
  • 灭火剂:水、二氧化碳、砂土、泡沫
  • MOL 文件:612-82-8.mol
  • TCI Shanghai:3,3'-二甲基联苯胺盐酸盐 o-Tolidine Dihydrochloride,>;98.0%(T)(612-82-8)
  • 盐酸-3,3'-二甲基联苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80130724 邻联甲苯胺盐酸盐 25g 21.7元 2011/04/16 T0254 邻联甲苯胺二盐酸盐 o-Tolidine Dihydrochloride 25G 441元 2011/04/16 T0254 邻联甲苯胺二盐酸盐 o-Tolidine Dihydrochloride 500G 4290元
  • Acros Organics:o-Tolidine dihydrochloride, 99%(612-82-8)
  • MSDS 信息:3,3'-Dimethylbenzidine dihydrochloride(612-82-8).msds
  • 急性毒性:口服-大鼠 LD50: 404 毫克/公斤; 腹腔-小鼠 LDL0: 125 毫克/公斤
  • 浅褐色至灰褐色结晶粉末，能溶于水和稀盐酸。
  • Alfa Aesar:邻甲苯胺二盐酸盐,ACS o-Tolidine dihydrochloride, ACS(612-82-8)
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amine Salts - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Biochemicals and Reagents
  4. Stains and Dyes
  5. Natural Dyes

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