1-Hexyne 1-己炔

CAS 693-02-7 MFCD00009504

化学结构图

693-02-7
SMILES: C#CCCCC

化学属性

Mol. FormulaC6H10
Mol. Weight82.14
Refractive index1.3980 to 1.4010
Boiling Point71-72
Density0.715
Melting Point-132
Flash Point-21°C(lit.)
TSCAYes
Vapor Pressure253 mmHg ( 37.7 °C)
Solubility不溶于水，溶于乙醇、乙醚、苯等。
Stability对空气敏感

别名和识别编码

Chemical Name1-Hexyne
CAS Number693-02-7
PubChem Substance ID12732
EC Number211-736-9
Beilstein Registry Number635687
MDL NumberMFCD00009504
Reaxys-RN635687
Synonym Butyl acetyne HEXYNE(1-) n-Butylacetylene 正丁基乙炔 1-hexine N-butylacetylene 1-已炔 丁基乙炔;正丁基乙炔 hex-1-yne Hexin-(1) N-BUTYLACETYLENE 丁基乙炔 5-Hexyne 1-hexyne Hexyne 1-Hexin 1-HEXYNE 1-己炔,98+% 1-Hexyne (8CI, 9CI) hexyne-1 1-己炔 Butylacetylene 1-Hexyne98% 1-Hexyne,>99% C4H9CequivCH Hex-1-yne
Chemical Name Translation1-己炔
LabNetwork Molecule IDLN00241730
InChIInChI=1S/C6H10/c1-3-5-6-4-2/h1H,4-6H2,2H3
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分类

  • Alkynes, Building Blocks, Chemical Synthesis, Organic Building Blocks, Terminal
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alkynes, Building Blocks, Chemical Synthesis, Organic Building Blocks, Terminal

产品应用

  • 用于有机合成。

相关文献及参考

  • Short: II/27B
  • The dilithiation of 1-alkynes with n-BuLi, followed by alkylation at the 3-position, is illustrated for 1-hexyne: Org. Synth. Coll., 6, 595 (1988). For [2 + 2] cycloaddition with dichloroketene to give a substituted cyclobutenone, see: Org. Synth. Coll., 8, 82 (1993).
  • Beilstein:1,253

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3
RTECSMQ9691000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
UN Number 3295
Packing GroupII
Hazard Class3
Storage condition 0-6°C 储存温度2-8°C 储存温度2-8℃,充氩保存
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NATUAS Nature.  (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736)
   V.1-    1869-  Volume(issue)/page/year: 174,737,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JACSAT Journal of the American Chemical Society.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1879-  Volume(issue)/page/year: 79,2311,1957

Restrict 危险品

其他信息

  • 蒸气压:253 mm Hg ( 37.7 °C)
  • 有特殊气味。
  • Sigma Aldrich:693-02-7(sigmaaldrich)
  • 海关编码:29012980
  • Hazard Note:Irritant
  • Acros Organics:1-已炔 1-Hexyne, 98%(693-02-7)
  • 灭火剂:干粉、干砂、二氧化碳、泡沫
  • 类别:易燃液体
  • 外观性质:水白色液体，有特殊气味。
  • MOL 文件:693-02-7.mol
  • 急性毒性:腹腔- 小鼠 LD50: 100 毫克/公斤; 皮下- 小鼠 LD50: 400 毫克/ 公斤
  • 1-己炔价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 H0140 1-己炔 1-Hexyne 25ML 364元 2011/04/16 H0140 1-己炔 1-Hexyne 250ML 2040元 2010/06/21 329901000 1-己炔 1-Hexyne 98% 100 ML 1205元
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾
  • 图谱信息:1-己炔(693-02-7)红外图谱(IR1) 1-己炔(693-02-7)核磁图( 1 HNMR) 1-己炔(693-02-7)核磁图( 13 CNMR) 1-己炔(693-02-7)Raman光谱 1-己炔(693-02-7)红外图谱(IR2)
  • 下游产品:炔丙菊酯 --> 4-己-1-炔基苯甲醛
  • 毒性分级:高毒
  • TCI Shanghai:1-己炔 1-Hexyne,>;97.0%(GC)(693-02-7)
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • F:10-23
  • MSDS 信息:1-己炔(693-02-7).msds
  • 1-己炔价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0140 1-己炔 1-Hexyne 25ML 349元 2014/06/02 H0140 1-己炔 1-Hexyne 250ML 1980元 2010/06/21 329901000 1-己炔 1-Hexyne 98% 100 ML 1205元
  • Alfa Aesar:1-己炔,98+% 1-Hexyne, 98+%(693-02-7)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkynes 炔
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkynes 炔
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkynes 炔
  5. Terminal - Alkynes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkynes 炔
  5. Internal
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Acetylenes 炔烃
  1. Life Science 生命科学
  2. 昆虫信息素