3-Methyl-1-phenyl-2-phospholene 1-oxide 3-甲基-1-苯基-2-环丁磷烯-1-氧化物

CAS 707-61-9 MFCD00014518

化学结构图

707-61-9
SMILES: CC1=CP(=O)(c2ccccc2)CC1

化学属性

Mol. FormulaC11H13OP
Mol. Weight192.19
TSCAYes
Boiling Point150 °C at 0.15 mmHg
Melting Point58-62 °C
Flash Point109°(228°F)
Refractive indexn20/D 1.5707(lit.)

别名和识别编码

Chemical Name2,3-Dihydro-4-Methyl-1-Phenyl-1H-Phosphole 1-Oxide
Synonym 3-Methyl-1-phenyl-2-phospholene 1-oxide {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {} {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-1-phenyl-2-phospholene 1-oxide {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00014518
CAS Number707-61-9
EC Number211-901-5
Beilstein Registry Number0609223
PubChem Substance ID69722
Reaxys-RN609223
Chemical Name Translation3-甲基-1-苯基-2-环丁磷烯-1-氧化物
InChIKeyYMKWWHFRGALXLE-UHFFFAOYSA-N
LabNetwork Molecule IDLN01743022
InChIInChI=1S/C11H13OP/c1-10-7-8-13(12,9-10)11-5-3-2-4-6-11/h2-6,9H,7-8H2,1H3
Canonical SMILESO=P1(C2=CC=CC=C2)CCC(C)=C1
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分类

  • {uni_hamburg} no charge; other heterocycle; carbocycle; aromatic; alicycle; 5ring; 6ring; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors

相关文献及参考

  • (previously believed to have the double bond in the 3-position)
  • Catalyst for conversion of isocyanates to carbodiimides: Org. Synth. Coll., 5, 501 (1973).
  • Short: EINECS
  • Short: III/35E

安全信息

RTECSSZ6105100
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Hygroscopic {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light
Hazard Codes Xn
GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 840 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DANKAS Doklady Akademii Nauk SSSR.  Proceedings of the Academy of Sciences
   of the USSR.  For English translation, see DBIOAM and DKBSAS.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-    1933-
   Volume(issue)/page/year: 160,826,1965

其他信息

  • Alfa Aesar:3-甲基-1-苯基-2-磷杂环戊烯-1-氧化物,94% 3-Methyl-1-phenyl-2-phospholene 1-oxide, 94%(707-61-9)
  • Sigma Aldrich:707-61-9(sigmaaldrich)
  • TCI Shanghai:3-甲基-1-苯基-2-环丁磷烯-1-氧化物 3-Methyl-1-phenyl-2-phospholene 1-Oxide,>;95.0%(GC)(707-61-9)
  • MOL 文件:707-61-9.mol
  • 敏感性:Hygroscopic
  • Acros Organics:3-甲基-1-苯基-2-磷 1-氧化物 3-Methyl-1-phenyl-2-phospholene oxide, 98%(707-61-9)
  • 3-甲基-1-苯基-2-磷 1-氧化物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0705 3-甲基-1-苯基-2-磷杂环戊烯-1-氧化物 3-Methyl-1-phenyl-2-phospholene 1-Oxide 5G 560元 2014/06/02 M0705 3-甲基-1-苯基-2-磷杂环戊烯-1-氧化物 3-Methyl-1-phenyl-2-phospholene 1-Oxide 25G 1680元 2010/05/25 44726 3-Methyl-1-phenyl-2-phospholene 1-oxide, 97% 25g 2982元
  • 图谱信息:3-甲基-1-苯基-2-磷 1-氧化物(707-61-9)核磁图( 13 CNMR) 3-甲基-1-苯基-2-磷 1-氧化物(707-61-9)核磁图( 1 HNMR)

系列性分类


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