Ethyl diphenylphosphinite 二苯基乙氧基膦
CAS 719-80-2 MFCD00009087
化学结构图
SMILES: CCOP(c1ccccc1)c1ccccc1
化学属性
| Mol. Formula | C14H15OP |
|---|---|
| Mol. Weight | 230.24 |
| Density | 1.066 |
| Refractive index | 1.5880 to 1.5920 |
| Flash Point | 176.4±23.4°C |
| TSCA | No |
| Boiling Point | 316.1±25.0°C at 760 mmHg |
| Melting Point | 164-167 °C |
别名和识别编码
| Chemical Name | Ethyl Diphenylphosphinite |
|---|---|
| CAS Number | 719-80-2 |
| EC Number | 211-951-8 |
| Beilstein Registry Number | 16(4)969 |
| MDL Number | MFCD00009087 |
| Synonym | Ethoxydiphenylphosphine {LY} Ethoxydiphenylphosphine {} {LY} Ethoxydiphenylphosphine {} {} {LY} Ethoxydiphenylphosphine {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} |
| PubChem Substance ID | 69754 |
| Reaxys-RN | 1641750 |
| Chemical Name Translation | 二苯基乙氧基膦 |
| InChIKey | JCRCPEDXAHDCAJ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00190184 |
| InChI | InChI=1S/C14H15OP/c1-2-15-16(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3 |
| Canonical SMILES | CCOP(C1=CC=CC=C1)C2=CC=CC=C2 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
相关文献及参考
- An iminophosphorane, formed with an azido ester (Staudinger), reacts with a carboxyl group to form an amide, providing the basis of a novel peptide coupling method. The reaction occurs at lower temperatures with this reagent rather than tributyl- or triphenylphosphine: J. Org. Chem., 50, 2601 (1985). See Appendix 6.
- Arbuzov reaction with alkyl halides gives diphenyl phosphine oxides, useful as Wittig-Horner intermediates. See, for example: Synthesis, 126 (1977); Tetrahedron Lett., 2433 (1979); Appendix 1.
- Beilstein:16(4)969
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P317
- P302+P352
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
其他信息
- MOL 文件:719-80-2.mol
- 二苯基乙氧基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2558 乙氧基二苯基膦 Ethoxydiphenylphosphine 5G 660元 2014/06/02 D2558 乙氧基二苯基膦 Ethoxydiphenylphosphine 25G 2160元 2010/06/21 165280050 二苯基乙氧基膦 Ethyl diphenylphosphinite 99% 5 GR 671元
- 溶于乙醇。
- Sigma Aldrich:719-80-2(sigmaaldrich)
- TCI Shanghai:二苯基乙氧基膦 Ethoxydiphenylphosphine,>;93.0%(T)(719-80-2)
- Alfa Aesar:二苯基乙氧基磷,98% Ethyl diphenylphosphinite, 98%(719-80-2)
- MSDS 信息:Ethyl diphenylphosphinite(719-80-2).msds
- Acros Organics:乙氧基二苯基磷 Ethyl diphenylphosphinite, 99%(719-80-2)
- 敏感性:Air & Moisture Sensitive
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