Iodoform 碘仿

CAS 75-47-8 MFCD00001069

化学结构图

75-47-8
SMILES: IC(I)I

化学属性

Mol. FormulaCHI₃
Mol. Weight393.73
Density4.008
Flash PointNone
TSCAYes
Melting Point>86°C (dec.)
Boiling Point
Solubility不溶. <0.1 G/100 ML AT 24 ºC
Stability对光敏感

别名和识别编码

Chemical NameIodoform
Synonym Dezinfekt V Iodoform IodoformB.P.C. Jodoform NCI-C04568 Triiodomethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00001069
CAS Number75-47-8
EC Number200-874-5
Merck Number14,5033
Beilstein Registry Number1697010
PubChem Substance ID6374
Chemical Name Translation碘仿
Wiswesser Line NotationIYII
LabNetwork Molecule IDLN00194351
InChIInChI=1S/CHI3/c2-1(3)4/h1H
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 生物化学，防腐。

相关文献及参考

  • Short: II/27B
  • Merck: 14,5033 Beilstein: 1,IV,97
  • Short: II/27C

安全信息

RTECSPB7000000
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 4 Light Sensitive 密封避光保存。
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312+H332
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Warning
Hazard Codes Xn
UN Number UN 1851 1851
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Amphibian - frog
DOSE/DURATION           : 606 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZEPTAT Zeitschrift fuer Experimentelle Pathologie und Therapie.  (Berlin,
   Ger.)  V.1-22, 1905-21. For publisher information, see REXMAS.
   Volume(issue)/page/year: 1,446,1905

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - muscle contraction or spasticity
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   ZEPTAT Zeitschrift fuer Experimentelle Pathologie und Therapie.  (Berlin,
   Ger.)  V.1-22, 1905-21. For publisher information, see REXMAS.
   Volume(issue)/page/year: 1

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 1 mg/L
REFERENCE :
   SHIGAZ Shigaku.  Ondotology.  (Nippon Shika Daigaku Shigakkai, 1-9-20
   Fujimi, Chiyodaku, Tokyo 102, Japan)  V.38-    1949-
   Volume(issue)/page/year: 74,1385,1987

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 10 mg/L
REFERENCE :
   SHIGAZ Shigaku.  Ondotology.  (Nippon Shika Daigaku Shigakkai, 1-9-20
   Fujimi, Chiyodaku, Tokyo 102, Japan)  V.38-    1949-
   Volume(issue)/page/year: 74,1385,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 1 mg/L
REFERENCE :
   SHIGAZ Shigaku.  Ondotology.  (Nippon Shika Daigaku Shigakkai, 1-9-20
   Fujimi, Chiyodaku, Tokyo 102, Japan)  V.38-    1949-
   Volume(issue)/page/year: 74,1385,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 67 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

Restrict 危险品

其他信息

  • Acros Organics:碘仿 Iodoform, 99+%(75-47-8)
  • 用途二:生物化学，防腐。
  • 图谱信息:碘仿(75-47-8)红外图谱(IR2) 碘仿(75-47-8)核磁图( 1 HNMR) 碘仿(75-47-8)质谱(MS) 碘仿(75-47-8)核磁图( 13 CNMR) 碘仿(75-47-8)红外图谱(IR1)
  • F:13
  • Alfa Aesar:碘仿,99% Iodoform, 99%(75-47-8)
  • MSDS 信息:三碘甲烷(75-47-8).msds
  • 方法一:由丙酮（或乙醇）经卤化、水解而得。先将水、碘化钠及丙酮加入反应锅，加冰降温至10℃。搅拌下缓缓加入次氯酸钠，直至不产生浑浊即达终点，控制温度不超过20℃。静置1h，吸去上层清液，取出碘仿层过滤。滤饼用水洗至中性，再用蒸馏水洗至无氯根为止。然后将其他35-40℃干燥，即得成品。此外，由氯仿与碘甲烷反应也可制备该品。
  • 有滑腻感，具刺激辛辣气味，能升华，加热温度高于熔点时，分解析出碘，能随水蒸气同时挥发，易溶于苯和丙酮，能溶于醇、醚、氯仿、二硫化碳和橄榄油，微溶于水、甘油和石油醚。
  • 用途一:在医芭和生物化学中用作防腐剂和消毒剂。小鼠口服LD50为910mg/kg。
  • 碘仿价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 81009026 三碘甲烷 100g 140元 2010/06/21 149125000 碘仿 Iodoform 99+% 500 GR 2136元 2010/06/21 149121000 碘仿 Iodoform 99+% 100 GR 577元
  • 外观性质:黄色粉末或晶体，有不愉快的气味。
  • 上游原料:氢氧化钠 --> 丙酮 --> 碘甲烷 --> 次氯酸钠
  • MOL 文件:75-47-8.mol
  • 下游产品:二碘甲烷
  • Sigma Aldrich:75-47-8(sigmaaldrich)
  • 敏感性:Light Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkanes 烷烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl