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分类

• Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chemical Class, Chromatography, D, DIA - DIC, Environmental Standards, Fluoro, Halogenated, Volatiles/ Semivolatiles
• {uni_hamburg} no charge; 1fragment

相关文献及参考

• Merck 14 ,3064
• Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
• Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
• Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchi

安全信息

GHS Symbol

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 80 pph/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJTXAZ European Journal of Toxicology and Environmental Hygiene.  (Paris,
   France)  V.7-9, 1974-76. For publisher information, see TOERD9.
   Volume(issue)/page/year: 9,385,1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3348 gm/m3/3H
TOXIC EFFECTS :
   Behavioral - sleep
   Behavioral - tremor
   Behavioral - excitement
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 28(6),95,1963

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >80 pph/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0520424

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 52(3),73,

其他信息

• 外观性质:无色无臭气体。
• 用途一:用作工业制冷剂、农药喷雾剂、发泡剂及溶剂等
• 爆炸物危险特性:高热钢并可爆
• 方法一:四氯化碳与氟化氢在五氯化锑催化剂存在下进行反应制得。当控制回流冷凝温度为-5℃时，主要得到本品。另一种生产方法是直接法，由甲烷与氯、无水氟化氢在流化床反应器中直接合成。
• 上游原料:四氯化碳 --> 氢氟酸 --> 五氯化锑
• 下游产品:四氟甲烷 --> 三氯氟甲烷 --> 氯三氟甲烷
• 用途二:该品是稳定的致冷剂，能得到-60℃的低温。也用作灭火剂、杀虫剂和烟雾剂。也是氟树脂的原料。广泛用于香料、医药、喷漆等工业。
• 毒性分级:低毒
• 职业标准:TWA 4950毫克/立方米;STEL 6200毫克/立方米
• 常规方法:用中压钢瓶包装，每瓶净重40kg。贮存于阴凉、通风处，贮运中严禁撞击和曝晒。
• 灭火剂:视周围化学品而定
• Hazard Note:Irritant
• Sigma Aldrich:75-71-8(sigmaaldrich)
• 可燃性危险特性:常温不燃; 燃烧产生有毒氟化物和氯化物烟雾
• 储运特性:库房通风低温干燥; 轻装轻卸; 与易燃物分开存放
• 急性毒性:吸入-小鼠 LC50: 3348000 毫克/ 立方米/ 3 小时
• 类别:不燃气体
• 防护措施:毒性很小，高浓度时有麻醉性。与火焰或热金属表面接触可能产生有毒物质。空气中最高容浓度0.001。
• MOL 文件:75-71-8.mol
• MSDS 信息:二氯二氟甲烷(75-71-8).msds