Lithium amide 氨基化锂

CAS 7782-89-0 MFCD00011093

化学结构图

7782-89-0
SMILES: [Li+].[NH2-]

化学属性

Mol. FormulaLiNH2
Mol. Weight23
Density1.178
Melting Point380-400
TSCAYes
Boiling Point430°
Solubility起反应
Appearance powder
RedoxReduction

别名和识别编码

Chemical NameLithium amide
Synonym Lithium amide (Li(NH2)) Lithamide Lithiumamid 鋰醯銨 Lithiumamide,95% Aminolithium Lithiumamideoffwhitepowder lithamide LITHIUM AMIDE, HYDROGEN STORAGE GRADE LITHIUM AMIDE, POWDER, 95% 氨基化锂; 氨基锂 Lithium amide LITHIUM AMIDE 氨基化锂 銨化鋰 lithium azanide Litium amide LiNH2 氨基锂 Lithioamine
MDL NumberMFCD00011093
CAS Number7782-89-0
EC Number231-968-4
Beilstein Registry Number2384789
Merck Number14,5522
PubChem Substance ID24532
Chemical Name Translation氨基化锂
LabNetwork Molecule IDLN02210660
InChIInChI=1S/Li.H2N/h;1H2/q+1;-1
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分类

  • {SA} Alternative Energy, Amides, Chemical Synthesis, Materials Science, Materials for Hydrogen Storage, Organic Bases, Synthetic Reagents
  • {SNA} Acids & Bases, Alternative Energy, Amides,
  • {SNA} Alternative Energy, Amides, Chemical Synthesis, Materials Science, Materials for Hydrogen Storage, Organic Bases, Synthetic Reagents
  • {SNA} Acids & Bases, Alternative Energy, Amides, Bases, Chemical Synthesis, Inorganic Bases, Materials for Hydrogen Storage, Synthetic Reagents, 材料科学
  • {SNA} Acids & Bases,
  • {SNA} 12 Principles Aligned Products,
  • {SNA} Acids & Bases,

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/7c1 Title: Crystal Structure Data of Inorganic Compounds: Key Element: N Author: Pies, W.; Weiss, A. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/7c1 Page: 1-260 Year: 1978 ISBN: 3-540-08674-9 ISBN: 978-3-540-08674-1 Internet Resource: DOI:10.1007/b19975 RefComment: 35 figs., XXV, Hardcover Abstract: Volume III/7 contains structure data on those compounds which contain at least one of the elements F, Cl, Br, I, O, N, and P and cannot be called "organic". The structure data of the remaining inorganic compounds and the elements are dealt with in volumes III/6 and III/14, while the organic compounds are treated in volumes III/5 and III/10. The systematic arrange-ment is based on the anions ordered according to "key elements", since this system allows the arrangement of the crystal structure data in such a way that both chemical and crystallographical relationships can be recognized. Structure data are compiled as completely as possible for all inorganic substances, where crystal structures have been examined by means of X-ray, neutron, and electron diffraction,and for which at least the lattice co

安全信息

Signal word Danger
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
Risk Statements
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P231+P232
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSOJ5590000
Packing GroupII
UN Number 1390 1390/1412 UN 1390 4.3/PG 2 UN1390
Storage condition water-free area Air & Moisture Sensitive
Hazard Codes 4.3 F,C
Hazard Class4.3
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • Alfa Aesar:氨基锂,95% Lithium amide, 95%(7782-89-0)
  • Sigma Aldrich:7782-89-0(sigmaaldrich)
  • MOL 文件:7782-89-0.mol
  • 氨基化锂价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 199860050 氨基化锂 Lithium amide 95% 5 GR 347元 2010/06/21 199865000 氨基化锂 Lithium amide 95% 500 GR 2112元 2010/06/21 199861000 氨基化锂 Lithium amide 95% 100 GR 601元
  • Acros Organics:氨基锂 Lithium amide, 95%(7782-89-0)
  • 下游产品:5-溴-2-(二甲基氨基)嘧啶
  • 外观性质:白色结晶或粉末,有氨的气味。
  • 敏感性:Air & Moisture Sensitive
  • MSDS 信息:氨基化锂(7782-89-0).msds

系列性分类


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