Benzene, 1,​1'-​sulfonylbis[4-​chloro- 4,4'-二氯二苯砜

CAS 80-07-9 MFCD00000619

化学结构图

80-07-9
SMILES: O=S(=O)(c1ccc(Cl)cc1)c1ccc(Cl)cc1

化学属性

Mol. FormulaC12H8Cl2O2S
Mol. Weight287.16
Density1.422
Boiling Point250
Melting Point143-146
Flash Point233°(451°F)
TSCAYes
Solubility<0.1 G/100 ML AT 20 ºC
Appearance 白色单斜结晶体。 不溶于水,微溶于冷乙醇。

别名和识别编码

Chemical NameBenzene, 1,​1'-​sulfonylbis[4-​chloro-
Synonym 4,4'-Dichlorodiphenyl sulfone {LY} 4,4'-Dichlorodiphenyl sulfone {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dichlorodiphenyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-
CAS Number80-07-9
EC Number201-247-9
Beilstein Registry Number2052955
MDL NumberMFCD00000619
PubChem Substance ID87563797
Chemical Name Translation4,4'-二氯二苯砜
Reaxys-RN2052955
Wiswesser Line NotationGR DSWR DG
LabNetwork Molecule IDLN00921362
Canonical SMILESO=S(C1=CC=C(Cl)C=C1)(C(C=C2)=CC=C2Cl)=O
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; sulfone; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfones, Sulfur Compounds

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/31b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zn ... Bi. Diagrams, Indexes Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31b Year: 1993 Keyword: NQR ISBN: 3-540-55147-6 ISBN: 978-3-540-55147-8 Internet Resource: DOI:10.1007/b46097 RefComment: 147 figs., VIII, 347 pages. Hardcover

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P305+P351+P338
RTECSWR3450000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xi,C Xi
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7500 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0533718

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 24 gm/kg
TOXIC EFFECTS :
   Behavioral - tremor
REFERENCE :
   HCACAV Helvetica Chimica Acta.  (Verlag Helvetica Chimica Acta, Postfach,
   CH-4002 Basel, Switzerland) V.1-    1918-  Volume(issue)/page/year:
   29,1317,1946

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 4,4'-二氯二苯砜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0810 4,4'-二氯二苯砜 4,4'-Dichlorodiphenyl Sulfone 25G 137元 2014/06/02 B0810 4,4'-二氯二苯砜 4,4'-Dichlorodiphenyl Sulfone 500G 1110元 2010/06/21 291182500 4,4'-二氯二苯砜 4,4'-Dichlorodiphenyl sulfone 97% 250 GR 520元
  • 敏感性:Moisture Sensitive
  • 储运特性:库房通风低温干燥
  • 急性毒性:口服-大鼠 LD50: >;20000 毫克/公斤; 口服-小鼠 LD50: 24000 毫克/公斤
  • MSDS 信息:Bis(4-chlorophenyl) sulfone(80-07-9).msds
  • TCI Shanghai:4,4'-二氯二苯砜 4,4'-Dichlorodiphenyl Sulfone,>;98.0%(GC)(80-07-9)
  • 海关编码:29309070
  • 毒性分级:低毒
  • Sigma Aldrich:80-07-9(sigmaaldrich)
  • 可燃性危险特性:可燃; 燃烧产生有毒硫氧化物和氯化物烟雾
  • 用途一:用作工程塑料聚砜的原料,也用于生产4,4'-二氨基二苯砜
  • Acros Organics:4,4'-二氯二苯基砜 4,4'-Dichlorodiphenyl sulfone, 97%(80-07-9)
  • MOL 文件:80-07-9.mol
  • Hazard Note:Harmful/Corrosive/Moisture Sensitive
  • 上游原料:三氯化铝 --> 氯苯
  • Alfa Aesar:4,4'-二氯二苯砜,98% Bis(4-chlorophenyl) sulfone, 99%(80-07-9)
  • 图谱信息:4,4'-二氯二苯砜(80-07-9)质谱(MS) 4,4'-二氯二苯砜(80-07-9)核磁图( 1 HNMR) 4,4'-二氯二苯砜(80-07-9)红外图谱(IR2) 4,4'-二氯二苯砜(80-07-9)核磁图( 13 CNMR) 4,4'-二氯二苯砜(80-07-9)红外图谱(IR1)
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 类别:有毒物品

系列性分类


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