1-Nitronaphthalene 1-硝基萘

CAS 86-57-7 MFCD00003913

化学结构图

86-57-7
SMILES: O=[N+]([O-])c1cccc2ccccc12

化学属性

Mol. FormulaC10H7NO2
Mol. Weight173
Boiling Point304 °C(lit.)
Density1.223 g/mL at 25 °C(lit.)
Melting Point56.0 to 59.0 deg-C
Flash Point164°(327°F)
TSCAYes
Solubility0.022 G/L

别名和识别编码

Chemical Name1-Nitronaphthalene
CAS Number86-57-7
PubChem Substance ID6849
EC Number201-684-5
Beilstein Registry Number5,553
MDL NumberMFCD00003913
Merck Number6613
Synonym 1-NITRONAPHTHALENE 1-Nitronaftalen 1-Nitronaphthalene 1-Nitronaphthalene (purity) 1-Nitronaphthalene,99% 1-Nitronaphthalin 1-Nitronaphthalin(a) 1-Nitronaphthalin(α) 1-Nitronphthalene 1-nitro-naphthalen 1-nitro-naphthalene 1-nitronaphthalene 1-nitronaphthalene (alpha) 1-nitronaphthalene (alpha-nitronaphthalene) 1-nitronapthalene 1-硝基萘 1-硝基萘, 99% 1-硝基萘,99% 1-硝基萘; alpha-硝基萘 35796, 1-Nitronaphthalene (purity) A-硝基萘 ALPHA-NITRONAPHTHALENE ALPHA-硝基萘 I-P#itronaphthalin NCI-C01956 Naphthalene,1-nitro- Nitrol Nitrol (pesticide) a-Nitronaphthalene a-Nitronaph
Chemical Name Translation1-硝基萘
Wiswesser Line NotationL66J BNW
LabNetwork Molecule IDLN01110257
Reaxys-RN1867714
InChIInChI=1S/C10H7NO2/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks
  • All PAH Standards, Alphabetic, Analytical Standards, Analytical/Chromatography, Application CRMs, CRMs, Certified Reference Materials (CRMs), Chromatography, Environmental CRM, Environmental Standards, N, NA - NI, Nitro-PAH, PAHs, Volatiles/ Semivolatiles, neat

产品应用

  • Usually used to study excited state dynamics of 1-nitropthalene in nonpolar, aprotic and protic solvents.

相关文献及参考

  • Short: II/27B
  • Merck: 14,6614 Beilstein: 5,IV,1673
  • Merck: 14,6614
  • Short: II/3

安全信息

GHS Symbol
WGK Germany2
Hazard Codes F,T,N T
Hazard statements
  • H228 Flammable solid 易燃固体
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSQJ9720000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P310+P330
  • P301+P312+P330
  • P302+P352
  • P302+P352+P312+P361+P364
  • P304+P340
  • P304+P340+P311
  • P305+P351+P338
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370 In case of fire: 在发生火灾的情况下:
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
UN Number UN 2538 4.1/PG 3 UN2538 2538
Risk Statements
  • R11 Highly flammable 非常易燃
  • R25 Toxic if swallowed 吞咽有毒
  • R51/53
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Packing GroupIII
Storage condition 2-8°C 密封阴凉通风处保存。
Hazard Class4.1
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 86 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Liver - hepatitis (hepatocellular necrosis), diffuse
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 4,253,1984

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 260 umol/L
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 13,2389,1992

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 19 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 192,239,1987

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 2 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 341,161,1995

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 20 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 259,111,1991

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 20 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-

Restrict 危险品

其他信息

  • 海关编码:29042000
  • MSDS 信息:1-硝基萘(86-57-7).msds
  • TCI Shanghai:1-硝基萘 1-Nitronaphthalene,>;98.0%(GC)(86-57-7)
  • 下游产品:1-萘胺 --> 新铜铁灵 --> 4-硝基1-萘胺
  • Alfa Aesar:1-硝基萘,99% 1-Nitronaphthalene, 99%(86-57-7)
  • Sigma Aldrich:86-57-7(sigmaaldrich)
  • Acros Organics:1-硝基萘 1-Nitronaphthalene, 99%(86-57-7)
  • 外观性质:黄色针状结晶。
  • 上游原料:萘 --> 搪玻璃反应锅
  • 无气味。易溶于氯仿、乙醚和二硫化碳,溶于乙醇,不溶于水。遇浓硫酸溶液呈暗红色。还原时生成1-萘胺。易燃。有毒。有刺激性。
  • 方法一:由萘经硝化而得。在实际工业生产中,反应所需的混酸,一部分可重复套用。将上批硝化所得的废酸600kg加入搪玻璃反应锅中,冷却下再加入300kg98%硫酸和793kg100%硝酸,将其进行搅拌配制成混酸待用。在反应锅中加入800kg上次硝化的废酸,投入1550kg精萘和上述配制的混酸,精萘和混酸分三次交叉加入,温度控制在50-55℃。加毕,升温至65℃,保温3h。取样检查终点,凝固点≥51℃时,分出硝化废酸。用热水将反应物洗至中性,即得1-硝基萘。
  • MOL 文件:86-57-7.mol
  • 用途一:用于制取染料、农药和橡胶防老剂等
  • 1-硝基萘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 147045000 1-硝基萘 1-Nitronaphthalene 99% 500 GR 443元 2010/06/21 147040050 1-硝基萘 1-Nitronaphthalene 99% 5 GR 164元 2010/05/25 L15725 1-硝基萘, 99% 1-Nitronaphthalene, 99% 25g 154元
  • 用途三:气相色谱固定液(最高使用温度100℃,溶剂为无水乙醇),分离芳烃。合成硫化染料和1-萘胺。掩蔽矿物油中荧光。
  • Hazard Note:Flammable/Toxic
  • 用途二:该品为染料、农药、橡胶助剂等有机合成的中间体。
  • 图谱信息:1-硝基萘(86-57-7)核磁图( 13 CNMR) 1-硝基萘(86-57-7)质谱(MS) 1-硝基萘(86-57-7)核磁图( 1 HNMR) 1-硝基萘(86-57-7)红外图谱(IR1) 1-硝基萘(86-57-7)红外图谱(IR2)

系列性分类


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