6-Tert-Butyl-m-Cresol 2-叔丁基-5-甲基苯酚

CAS 88-60-8 MFCD00002308

化学结构图

88-60-8
SMILES: CC1CCC(C(C)(C)C)C(O)C1

化学属性

Mol. FormulaC11H16O
Mol. Weight164.24
Refractive index1.5170 to 1.5210
Boiling Point224 °C at 760 mmHg
Density0.964
Flash Point106 ºC
Melting Point20 °C
Appearance 针状结晶。熔点46-47℃，沸点244℃，127℃（1.46kPa），也有报道117-118℃（1.6kPa），闪点107℃ ，相对密度0.964（20/4℃），折光率1.5192。闪点105℃。

别名和识别编码

Chemical Name6-Tert-Butyl-m-Cresol
Synonym 2-tert-Butyl-5-methylphenol {LY} 2-tert-Butyl-5-methylphenol {} {LY} 2-tert-Butyl-5-methylphenol {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {} {} {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-tert-Butyl-5-methylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-tert-Butyl-5-
CAS Number88-60-8
PubChem Substance ID87563719
EC Number201-842-3
MDL NumberMFCD00002308
Reaxys-RN1908225
Beilstein Registry Number6(3)1982
Chemical Name Translation2-叔丁基-5-甲基苯酚
LabNetwork Molecule IDLN00224261
Canonical SMILESCC1=CC(=C(C=C1)C(C)(C)C)O
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分类

  • {SA} Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment

相关文献及参考

  • Beil. 6 ,II,507
  • Corp MSDS 1 (1), 641:D / FT-IR 2 (2), 1858:C / FT-NMR 1 (2), 267:A / IR-Spectra (2), 583:D / IR-Spectra (3), 654:A / NMR-Reference 2 (1), 882:C / RegBook 1 (1), 1279:A / Structure Index 1 , 194:C:7 / Vapor Phase 3 , 1021:D
  • Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/8I Title: Densities of Phenols, Aldehydes, Ketones, Carboxylic Acids, Amines, Nitriles, and Nitrohydrocarbons Author: Frenkel, M.; Hong, X.; Dong, Q.; Yan, X.; Chirico, R.D. Editor: Frenkel, M.; Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8I Year: 2002 Keyword: Thermodynamics; Thermodynamik ISBN: 978-3-540-42883-1 ISBN: 3-540-42883-6 Internet Resource: DOI:10.1007/b76771 RefComment: XI, 470 p., Hardcover RefComment: Written for Scientists and engineers in the fields of Physics, Chemistry and Physical Chemistry Abstract: Critically evaluated experimental data covering the densities of organic compounds are essential for both scientific and industrial applications. Knowledge of densities is important in many areas, including custody transfer of materials, product specification, development of various predictive methods, and for characterizing compounds a

安全信息

GHS Symbol
WGK Germany2
Hazard Codes Xn
Hazard statements
  • H302+H312
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSSK1578180
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P308+P311
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
Signal word
UN Number 2430
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Packing GroupIII
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1080 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAPMA8 Journal of the American Pharmaceutical Association, Scientific
   Edition.  (Washington, DC) V.29-49, 1940-60.  For publisher information, see
   JPMSAE.  Volume(issue)/page/year: 38,366,1949

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:88-60-8(sigmaaldrich)
  • 上游原料:氯化锌 --> 叔丁醇 --> 异丁烯 --> 间甲酚
  • 毒性分级:中毒
  • MSDS 信息:6-tert-Butyl-m-cresol(88-60-8).msds
  • 图谱信息:6-叔丁基间甲酚(88-60-8)核磁图( 1 HNMR) 6-叔丁基间甲酚(88-60-8)核磁图( 13 CNMR) 6-叔丁基间甲酚(88-60-8)红外图谱(IR1) 6-叔丁基间甲酚(88-60-8)质谱(MS)
  • TCI Shanghai:2-叔丁基-5-甲基苯酚 6-tert-Butyl-m-cresol,>;97.0%(GC)(88-60-8)
  • 6-叔丁基间甲酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0718 6-叔丁基间甲酚 6-tert-Butyl-m-cresol 500G 1260元 2014/06/02 B0718 6-叔丁基间甲酚 6-tert-Butyl-m-cresol 25G 277元 2010/06/21 403510050 6-叔丁基间甲酚 6-tert-Butyl-m-cresol 98% 5 GR 370元
  • 下游产品:4,4'-硫代双(6-特丁基间甲酚)
  • 方法一:由间甲酚与异丁烯在三氯化铝存在下反应而得。反应在浓硫酸中进行，反应温度为310-320℃。反应完成后，经中和、蒸馏而得成品。
  • MOL 文件:88-60-8.mol
  • 灭火剂:水, 干粉, 二氧化碳, 泡沫
  • 可燃性危险特性:遇热, 明火, 氧化剂易燃;热分解排出辛辣刺激烟雾
  • 急性毒性:口服-小鼠 LD50: 1080 毫克/公斤
  • 储运特性:库房低温干燥通风; 与氧化剂分开存放
  • 用途二:有机合成中间体。用于生产酚类抗氧剂CA、抗氧剂300、抗氧剂BBM。
  • 用途一:用作300、CA等抗氧剂中间体
  • Acros Organics:2-叔丁基-5-甲基苯酚(1KG不再生产) 6-tert-Butyl-m-cresol, 98%(88-60-8)
  • 类别:易燃液体

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C9 to C20+ - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Protected Alcohols/Phenols - Oxygen Compounds

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