Iron(0) pentacarbonyl

CAS 13463-40-6 MFCD00011001

化学结构图

13463-40-6
SMILES: [Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

化学属性

Refractive indexn20/D 1.5196(lit.)
SolubilitySoluble in nickel tetracarbonyl and organic solvents. Insoluble in water
TSCAYes
Autoignition Point122 °F
Vapor Density6.74 (vs air)
Vapor Pressure35 mmHg ( 25 °C)
Mol. FormulaC5FeO5
Mol. Weight195.90
Density1.490
Flash Point5°F
Appearance orange liq.
Stabilityair sensitive, store cold
Boiling Point103°C
Melting Point-20°C

别名和识别编码

Chemical NameIron(0) pentacarbonyl
Synonym Iron pentacarbonyl (Fe(CO)5) ironpentacarbonyl 羰基铁 Pentacarbonyliron Eisenpentacarbonyl R 20 Iron, pentacarbonyl- pentacarbonyliron Pentacarbonyleisen Pentacarbonyliron(0) Iron pentacarbonyl Fe (CO)5 FER pentacarbonyle pentacarbonyl iron Iron carbonyl (Fe(CO)5), (TB-5-11)- Iron pentacarbonyl (liquid) 五羰基铁
EC Number236-670-8
Merck Number14,5099
PubChem Substance ID24851709
Wiswesser Line NotationFE C-O*4
MDL NumberMFCD00011001
CAS Number13463-40-6
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分类

  • {uni_hamburg} no charge; metal-organic; metal carbonyl; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron

相关文献及参考

  • 1. Chen, L.-G.; et al., Addition reaction of Fe(CO)n (n = 3~5) on fullerene C50, C60, and C70: A density functional theory study Chin. J. Structural Chem. 30 , 1161, (2011)
  • 2. Amarasinghe, D. S.; et al., Effect of CO Pressure Gradients on the Photochemistry and Thermal Chemistry of Fe(CO)5 Physisorbed into Porous Vycor Glass J. Phys. Chem. C 115 , 20824, (2011)
  • 3. Snovski, R.; et al., Novel magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution J. Magn. Magn. Mater. 324 , 90, (2011)
  • 4. Tsutsumi, H.; et al., New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides Chem. Commun. 47 , 6581, (2011)
  • 5. Yamada, Y.; et al., Photocatalytic Hydrogen Evolution under Highly Basic Conditions by Using Ru Nanoparticles and 2-Phenyl-4-(1-naphthyl)quinolinium Ion J. Am. Chem. Soc. 133 , 16136, (2011)
  • Merck 14 ,5099
  • Fieser 1 ,519 / Fieser 2 ,229 / Fieser 3 ,167 / Fieser 4 ,268 / Fieser 5 ,357 / Fieser 6 ,304 / Fieser 10 ,221 / Fieser 13 ,152 / Fieser 17 ,270
  • Aldrich MSDS 1 , 1107:D / Corp MSDS 1 (1), 2014:C / FT-IR 1 (2), 1298:A / FT-IR 2 (3), 4591:D / IR-Spectra (3), 1566:B / RegBook 1 (2), 3141:I / Sax 6 , 1626 / Vapor Phase 3 , 1690:C
  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other param

安全信息

RTECSNO4900000
UN Number UN1994
Risk Statements
  • R11 Highly flammable 非常易燃
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition Air Sensitive
GHS Symbol
WGK Germany2
Hazard Codes F,T+
Hazard statements
  • H300+H330
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
Signal word Danger
Packing GroupI
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 11 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 25,415,1943

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 910 mg/m3/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 19

T

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 250 ppm/45M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,335,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 910 mg/m3/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 19,11,1959

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROU

TYPE OF TEST            : LD50 - Lethal dose, 5

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Iron - 铁催化剂
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Iron - CVD and ALD Precursors by Metal
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Iridium
  1. CVD & ALD Precursors
  2. Iron
  1. Metal Carbonyls
  2. Iron
  1. Metal Carbonyls for CVD & ALD
  2. Iron

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