Lithium Tetrachlorocuprate 四氯合铜酸二锂

CAS 15489-27-7 MFCD00011081

化学结构图

15489-27-7
SMILES: Cl[Cu-2](Cl)(Cl)Cl.[Li+].[Li+]

化学属性

TSCANo
Flash Point-17°C(lit.)
Density0.89
Mol. FormulaLi2CuCl4
Mol. Weight219.00

别名和识别编码

Chemical NameLithium Tetrachlorocuprate
CAS Number15489-27-7
PubChem Substance ID11074879
EC Number203-726-8
MDL NumberMFCD00011081
Beilstein Registry Number2384789
Synonym 四氯合铜酸二锂(II) 溶液
Chemical Name Translation四氯合铜酸二锂
Reaxys-RN14202500
InChIKeyHCJWWBBBSCXJMS-UHFFFAOYSA-J
InChIInChI=1S/4ClH.Cu.2Li/h4*1H;;;/q;;;;+2;2*+1/p-4
LabNetwork Molecule IDLN01742056
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分类

  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Lithium Salts, Materials Science, Metal and Ceramic Science, Salts
  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Essential Chemicals,

相关文献及参考

  • 1. Tetrahedron 62 , 4851, (2006)
  • Fieser 4 ,163 / Fieser 5 ,226 / Fieser 6 ,203 / Fieser 7 ,114 / Fieser 8 ,176 / Fieser 11 ,190 / Fieser 12 ,195
  • Aldrich MSDS 1 , 726:A / Corp MSDS 1 (1), 1302:C

安全信息

GHS Symbol
WGK Germany2
Hazard Codes 3
Hazard statements
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P311
  • P403+P233
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
UN Number 1993 UN2056
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Storage condition Moisture Sensitive
Packing GroupII
Hazard Class3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Copper Catalysis 铜催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Lithium - Catalysis and Inorganic Chemistry
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Lithium Salts 锂盐
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Cobalt
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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