Nickel peroxide 过氧化镍

CAS 12035-36-8 MFCD00011143

化学结构图

12035-36-8
SMILES: [O-2].[Ni+2]

化学属性

Mol. FormulaNiO2
Mol. Weight90.69
Solubility不溶于水,溶于硫酸、硝酸、盐酸、氨水。
Density4.83

别名和识别编码

Chemical NameNickel peroxide
Synonym {uni_hamburg} C.I. 77777 过氧化镍 green nickel oxide NiO2 Nickeldioxid 氧化镍黑 Nickel(IV)oxid Nickel dioxide nickeloxide(ni2o3) NICKEL OXIDE 黑色氧化镍 NICKEL SESQUIOXIDE NICKEL (III) OXIDE-GREY BLACK dinickeltrioxide NickelOxide,Black,Powder Nickel(Ⅲ)oxide NICKEL (III) OXIDE BLACK NICKEL PEROXIDE NICKEL OXIDE BLACK (IC) NICKELIC OXIDE Nickel oxide Nickel peroxide 三氧化二镍 氧化高镍 Nickelperoxid Nickel oxide (NiO2) Greyblack nickeltrioxide NICKEL OXIDE, BLACK nickeloxideperoxide Powder
MDL NumberMFCD00011143
PubChem Substance ID57652407
EC Number234-823-3
CAS Number12035-36-8
Chemical Name Translation过氧化镍
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel, Oxidizing Agents, Peroxides, Synthetic Reagents
  • {Chemicalbook} 无机化工产品: 无机盐: Ct氧化物
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel Catalysts, Oxidizing Agents, Peroxides, Syn

相关文献及参考

  • Short: III/7b1 Title: Crystal Structure Data of Inorganic Compounds: Key Element : O Author: Pies, W.; Weiss, A. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/7b1 Page: 1-674 Year: 1975 ISBN: 3-540-06919-4 ISBN: 978-3-540-06919-5 Internet Resource: DOI:10.1007/b19973 RefComment: 23 figs., XXIII, Hardcover Abstract: Volume III/7 contains structure data on those compounds which contain at least one of the elements F, Cl, Br, I, O, N, and P and cannot be called "organic". The structure data of the remaining inorganic compounds and the elements are dealt with in volumes III/6 and III/14, while the organic compounds are treated in volumes III/5 and III/10. The systematic arrange-ment is based on the anions ordered according to "key elements", since this system allows the arrangement of the crystal structure data in such a way that both chemical and crystallographical relationships can be recognized. Structure data are compiled as completely as possible for all inorganic substances, where crystal structures have been examined by means of X-ray, neutron, and electron diffraction,and for which at least the lattice constants have been determined.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
Precautionary statements
  • P308+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
Hazard statements
  • H350 May cause cancer 可能致癌
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
WGK Germany1
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Hazard Codes T
Risk Statements
  • R48/23
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
  • R49 May cause cancer by inhalation 吸入会致癌
Packing GroupIII
Hazard Class5.1
UN Number UN 1479 5.1/PG 2

其他信息

  • MOL 文件:1314-06-3.mol
  • 氧化镍价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 51016760 三氧化二镍 10g 67元 2011/08/23 20029227 黑色氧化镍 250g 108元
  • 用途一:用作陶瓷和玻璃的颜料。
  • 用途二:用于制蓄电池、镍粉、电子元件及用作陶瓷、玻璃、搪瓷的颜料等
  • 用途三:用作陶瓷、玻璃、搪瓷的着色颜料。也用于镍粉的制造及磁性体的研究。
  • 图谱信息:氧化镍(1314-06-3)红外图谱(IR1)
  • F:10
  • 毒性:参见一氧化镍。
  • 下游产品:工搪琅粉
  • 用途四:氧的发生剂,电镀,铁氧体原料。
  • 方法一:碳酸镍煅烧法先将金属镍制成硫酸镍溶液,再与碳酸钠进行复分解反应,生成物经过滤除去硫酸钠、再经浓缩、冷却结晶、离心分离、干燥,所得干燥碳酸镍经煅烧、球磨粉碎,制得三氧化二镍。其 NiSO4+Na2CO3→NiCO3+Na2SO4 2NiCO3[△]→Ni2O3+CO↑+CO2↑
  • 外观性质:黑色、有光泽的粉末。
  • 上游原料:硝酸 --> 镍 --> 硫酸镍 --> 碳酸镍
  • MSDS 信息:三氧化二镍(1314-06-3).msds
  • 参考质量标准:部颁标准HGB 3534—62 指标名称 指标 三氧化二镍(以Ni计)/%≥ 60 盐酸不溶物/%< 0.2 氯化物/%< 0.01 硫酸盐/%< 0.06 硝酸盐/%< 0.05 重金属(Cu)/%< 0.01 铁/%< 0.003 钴/%< 0.2 碱金属或碱土金属/%< 0.3

系列性分类


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