Lead(II) fluoride 氟化铅(II)

CAS 7783-46-2 MFCD00011162

化学结构图

7783-46-2
SMILES: F[PbH2]F

化学属性

Mol. FormulaF2Pb
Mol. Weight245.19
Density8.445
Melting Point855°
TSCAYes
Boiling Point1290°
Solubility0.065 G/100 ML (20 ºC)
Flash Point1290°C
Appearance powder

别名和识别编码

Chemical NameLead(II) fluoride
CAS Number7783-46-2
PubChem Substance ID24549
EC Number231-998-8
MDL NumberMFCD00011162
Merck Number14,5408
Synonym Blei(II)-fluorid Bleifluorid LEAD DIFLUORIDE LEAD FLUORIDE LEAD(+2)FLUORIDE LEAD(II) FLUORIDE LEAD(II) FLUORIDE, 99.99% LEAD(II) FLUORIDE, POWDER, CA. 5 MICRON, 99+% Lead difluoride Lead difluoride (PbF2) Lead fluoride (PbF2) Lead fluoride, alpha Lead(2+) fluoride Lead(II) fluoride Lead(II)fluoride,99%(metalsbasis) Lead(II)fluoride,99.5%min Lead(Ii)Fluoride>96% Lead(Ⅱ) fluoride NA 2811 PbF2 Plomb fluorure Plumbous fluoride lead (II) fluoride lead fluoride lead fluoride (PbF2) lead fluoride (PbF3) lead(+2) fluoride lead(II) fluoride leadfluoride(pbf2) {Chemicalb
Chemical Name Translation氟化铅(II)
Wiswesser Line NotationPB F2
LabNetwork Molecule IDLN00226216
InChIInChI=1S/2FH.Pb/h2*1H;/q;;+2/p-2
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分类

  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Lead, Lead Salts, Materials Science, Metal and Ceramic Science, Salts
  • {uni_hamburg} no charge; 3fragments; ionic
  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Lead, Lead Salts, Materials Science, Metal and Ceramic Science, Salts
  • {SNA} Alternative Energy, Catalysis and Inorganic Chemistry, Chemical Synthesis, Dopants, Lead, Lead Salts, Materials Science, Metal and Ceramic Science, Phosphor Materials,

产品应用

  • 作为温和氟化剂,用于转化钼和钨的氧化物或氢氧化物成氟化物。用作四氟化铅的原料。还用于特种玻璃制造,水下构件的油漆组分。

相关文献及参考

  • Merck: 14,5408
  • Short: II/25A
  • Short: EINECS

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T,N T;N
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H332 Harmful if inhaled 吸入有害
  • H340 May cause genetic defects 可能导致遗传性缺陷
  • H350 May cause cancer 可能致癌
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSOG1225000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P307+P311
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
UN Number UN 2291 6.1/PG 3 UN2291 2291
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R33 Danger of cumulative effects 有累积作用的危险
  • R50/53
Packing GroupIII
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Amphibian - frog
DOSE/DURATION           : 2800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses
   Filiales.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.1-    1849-
   Volume(issue)/page/year: 124,133,1937

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3031 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - respiratory stimulation
   Skin and Appendages - hair
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 35(8),43,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3015 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - respiratory stimulation
   Skin and Appendages - hair
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 35(8),43,1991

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 50 mg/m3/4H
SEX/DURATION            : male 17 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 57(3),28,1992

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 5 mg/m3/4H
SEX/DURATION            : male 17 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 57(3),28,1992

其他信息

  • MOL 文件:7783-46-2.mol
  • 储运特性:库房通风低温干燥; 与酸类、食品添加剂分开存放
  • 外观性质:白色结晶或粉末。
  • Alfa Aesar:氟化铅(II),Puratronic|r,99.997%(metalsbasis) Lead(II) fluoride, Puratronic, 99.997% (metals basis)(7783-46-2)
  • 毒性分级:中毒
  • Acros Organics:Lead(II) fluoride, 99.99%(7783-46-2)
  • 用途一:作为温和氟化剂,用于转化钼和钨的氧化物或氢氧化物成氟化物。用作四氟化铅的原料。还用于特种玻璃制造,水下构件的油漆组分。
  • Sigma Aldrich:7783-46-2(sigmaaldrich)
  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 4.634×10-2/20℃
  • TSCA:Yes
  • 可燃性危险特性:不燃; 遇酸放出有毒的氟化氢气体; 受热产生有毒氟化物和含铅化物烟雾
  • Hazard Note:Toxic
  • 职业标准:TLV-TWA 0.15 毫克(铅)/ 立方米
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • MSDS 信息:二氟化铅(7783-46-2).msds
  • 急性毒性:口服-大鼠 LD50: 3031 毫克/公斤; 口服-小鼠 LD50: 3015 毫克/ 公斤
  • 氟化铅价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80073318 氟化铅 500g 58.9元 2010/06/21 318291000 氟化铅 Lead(II) fluoride 99+%, powder, ca. 5 micron 100 GR 449元 2010/06/21 212520250 氟化铅 Lead(II) fluoride 99.99% 25 GR 1087元
  • 溶于硝酸,稍溶于无水氟化氢,难溶于水,不溶于丙酮和液氨。有毒!由氢氟酸与碳酸铅或氢氧化铅反应制得。也可由氟化铵或氟化钾与硝酸铅或醋酸铅反应制得。
  • 类别:有毒物品

系列性分类


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