Antimony trifluoride 氟化锑

CAS 7783-56-4 MFCD00011218

化学结构图

7783-56-4
SMILES: F[Sb](F)F

化学属性

Mol. FormulaSbF3
Mol. Weight179
Density4.38
Melting Point235
TSCAYes
Boiling Point376°C
SolubilitySoluble in water (4430 mg/ml at 20 °C), methanol (1540 mg/ml), and acetone. Insoluble in ammonia.
Flash Point376°C
Appearance powder
Stability对湿度敏感

别名和识别编码

Chemical NameAntimony trifluoride
Synonym ANTIMONY FLUORIDE, TRI ANTIMONY TRIFLUORIDE ANTIMONY(III) FLUORIDE Antimoine fluorure Antimon(III)-fluorid Antimontrifluorid Antimony trifluoride Antimony trifluoride; Trifluorostibine Antimony(III) fluoride Antimony(iii) fluoride (1:3) NA 1549 Stibine, trifluoro- Trifluorostibine Trifluorostibine 三氟化锑 antimoinefluorure antimoinefluorure(french) antimonousfluoride antimony (III) fluoride antimony(iii)fluoride(1:3) trifluoro-stibin trifluorostibine 三氟化锑 三氟化锑,氟化亚锑 三氟化锑; 氟化亚锑 氟化銻 氟化锑(III) 氟化锑, 99+%
CAS Number7783-56-4
EC Number232-009-2
Beilstein Registry Number2384789
MDL NumberMFCD00011218
PubChem Substance ID24554
Merck Number14,709
Chemical Name Translation氟化锑
LabNetwork Molecule IDLN01255692
InChIInChI=1S/3FH.Sb/h3*1H;/q;;;+3/p-3
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分类

  • {SNA} Antimony, Antimony Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Materials Science, Metal and Ceramic Science, Research Essentials, Salts
  • {SNA} Antimony Catalysts, Antimony Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, 材料科学
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Antimony, Antimony Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials,

产品应用

  • 氟化反应催化剂,氯氟化合物的制备。棉织物的媒染剂。

相关文献及参考

  • Merck: 14,709
  • Short: III/20c
  • Short: III/31b

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R51/53
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P312
  • P301+P330+P331
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RTECSCC5150000
Packing GroupII
UN Number 3260 UN 3260 8/PG 2
Storage condition Moisture Sensitive 充氩保存 密封干燥保存。 Hygroscopic
Hazard Codes 8 T,N
Hazard Class8
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 三氟化锑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 191240050 三氟化锑 Antimony trifluoride 98% 5 GR 291元 2010/06/21 191241000 三氟化锑 Antimony trifluoride 98% 100 GR 475元 2010/06/21 191245000 三氟化锑 Antimony trifluoride 98% 500 GR 1573元
  • 毒性分级:高毒
  • MOL 文件:7783-56-4.mol
  • 可燃性危险特性:不燃; 遇水或酸放出腐蚀的氟化氢气体; 受热产生有毒氟化物和含锑化物烟雾
  • 职业标准:TWA 0.5 毫克(锑)/ 立方米; STEL 2.5 毫克 (氟)/立方米
  • 升华点:376 °C
  • MSDS 信息:三氟化锑(7783-56-4).msds
  • 用途二:氟化反应催化剂,氯氟化合物的制备。棉织物的媒染剂。
  • Sigma Aldrich:7783-56-4(sigmaaldrich)
  • 急性毒性:皮下- 小鼠 LDL0: 22.9 毫克/ 公斤; 口服- 小鼠 LD50: 804 毫克/ 公斤
  • Acros Organics:三氟化锑 Antimony trifluoride, 98%(7783-56-4)
  • Alfa Aesar:氟化锑,99+% Antimony(III) fluoride, 99+%(7783-56-4)
  • 敏感性:Moisture Sensitive
  • 有吸湿性、腐蚀性;溶于水,水中溶解度: 385 G/100ML (20°C),并产生一定程度的水解,生成[SbF4]-和许多溶解性盐,不溶于氨水。有毒,最小致死量(蛙,皮下)224mg/kg。对皮肤有刺激性。
  • F:10
  • 储运特性:库房通风低温干燥; 与酸类、食品添加剂分开存放
  • Hazard Note:Corrosive/Highly Toxic
  • 外观性质:白色至灰色结晶, 易潮解。
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 385g/0℃;444g/20℃;562g/30℃;水解/40℃
  • 用途一:用作分析试剂和棉织物的媒染剂
  • 类别:有毒物品

系列性分类