Ammonium sulfamate 氨基磺酸铵

CAS 7773-06-0 MFCD00011429

化学结构图

7773-06-0
SMILES: NS(=O)(=O)[O-].[NH4+]

化学属性

Mol. FormulaH6N2O3S
Mol. Weight114.12
Melting Point131-135 °C
SolubilityVery soluble in water, liquid ammonia. Slightly soluble in ethanol, glycerol, glycol
TSCAYes
Boiling Point160 °C at 760 mmHg
Density1.8
Flash Point160°C

别名和识别编码

Chemical NameAmmonium sulfamate
CAS Number7773-06-0
PubChem Substance ID24482
EC Number231-871-7
MDL NumberMFCD00011429
Reaxys-RN13191688
Merck Number554
Synonym Ammonium sulfamate {LY} Ammonium sulfamate {} {LY} Ammonium sulfamate {} {} {LY} Ammonium sulfamate {} {} {} {LY} Ammonium sulfamate {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium sulfamate {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation氨基磺酸铵
Wiswesser Line NotationZSWQ &ZH
LabNetwork Molecule IDLN00194974
InChIInChI=1S/H3NO3S.H3N/c1-5(2,3)4;/h(H3,1,2,3,4);1H3
Canonical SMILES[NH4SO3NH2]
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分类

  • {SNA} Ammonium, Chemical Synthesis, Inorganic Salts, Synthetic Reagents
  • {SNA} A-B, Puriss p.a., Ammonium Salts, Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Essential Chemicals, Puriss p.a., Research Essentials, Salts
  • {SNA} A-B, Puriss p.a., Ammonium Salts, Analytical Reagents for General Use, Essential Chemicals, Puriss p.a., Research Essentials, Salts,
  • {SNA} Ammonium,
  • {SA} Analytical Standards, Analytical/Chromatography, BioUltra, Chromatography, Environmental Standards, Herbicides,
  • {SNA} A-B, Puriss p.a.,

产品应用

  • 织物及纸张的防火剂,除草剂,氧化亚氮发生剂。

相关文献及参考

  • Short: EINECS
  • Short: IV/1b
  • Merck: 14,554

安全信息

GHS Symbol
WGK Germany1
Hazard Codes Xn Xn,N
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H332 Harmful if inhaled 吸入有害
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSWO6125000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning {} {} {} {TCI}
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R50 Very toxic to aquatic organisms 对水生生物极毒
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
UN Number UN 3077 9/PG 3 9089/3077
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,178,1956

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 800 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 25,26,1943

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 4,316,1952

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3100 mg/kg
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow

其他信息

  • 职业标准:TWA 10 毫克/立方米
  • 急性毒性:口服- 大鼠 LD50: 2000 毫克/ 公斤; 口服- 小鼠 LD50: 3100 毫克/ 公斤
  • 毒性分级:中毒
  • 可燃性危险特性:燃烧产生有毒氮氧化物和硫氧化物气体
  • 灭火剂:干粉、泡沫、砂土
  • Acros Organics:氨基磺酸铵 Ammonium sulfamate, 99+%(7773-06-0)
  • TCI Shanghai:氨基磺酸铵 Ammonium Amidosulfate,>;98.5%(T)(7773-06-0)
  • 敏感性:Air & Moisture Sensitive
  • 氨基磺酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30012416 氨基磺酸铵 100g 23元 2011/04/16 S0117 氨基磺酸铵 Ammonium Amidosulfate 25G 156元 2011/04/16 S0117 氨基磺酸铵 Ammonium Amidosulfate 500G 499元
  • 用途二:广泛用于农药、印染、烟草、建材、纺织等行业
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 类别:农药
  • F:3-10
  • 外观性质:白色大块结晶。易潮解,在160℃时分解。极易溶于水,能溶于甘油、乙二醇和甲酰胺,微溶于醇。熔点:131-135℃
  • 下游产品:咪草烟 --> 防染剂 H --> 1,2-萘醌-4-磺酸钾盐 --> 2-羟基-1,4-萘醌 --> 2-氨基-3-吡啶甲醛盐酸盐 --> 环己基氨基磺酸钙 --> 高温匀染剂 10,匀染剂 A-10 --> 氨基磺酸胍
  • Sigma Aldrich:7773-06-0(sigmaaldrich)
  • MOL 文件:7773-06-0.mol
  • Alfa Aesar:磺酸铵,ACS,98%min Ammonium sulfamate, ACS, 98% min(7773-06-0)
  • 上游原料:氢氧化铵 --> 氨基磺酸 --> 碳酸铵 --> 4-三氟甲基茴香硫醚
  • 图谱信息:氨基磺酸铵(7773-06-0)质谱(MS) 氨基磺酸铵(7773-06-0)红外图谱(IR1) 氨基磺酸铵(7773-06-0)红外图谱(IR2)
  • 用途一:用作分析试剂、除草剂及织物防水剂
  • 易潮解,在160℃时分解。极易溶于水,能溶于甘油、乙二醇和甲酰胺,微溶于醇。
  • 用途三:织物及纸张的防火剂,除草剂,氧化亚氮发生剂。
  • 爆炸物危险特性:受热可爆; 在热酸溶液中自发爆炸

系列性分类