Trichlorosilane 三氯硅烷

CAS 10025-78-2 MFCD00011518

化学结构图

10025-78-2
SMILES: Cl[SiH](Cl)Cl

化学属性

Mol. FormulaHCl3Si
Mol. Weight135
Density1.342
Vapor Density1 (vs air)
Boiling Point32-34
Vapor Pressure9.75 psi ( 20 °C)
Refractive index1.4000 to 1.4030
Flash Point-13°(7°F)
SolubilitySoluble in benzene, CS2, chloroform, CCl4
TSCAYes
Melting Point-127°
Stability对空气和湿度敏感

别名和识别编码

Chemical NameTrichlorosilane
Synonym Silicon chloride hydride (SiCl3H) Trichlorosilane (SiHCl3) 三氯氢硅 Silicochloroform Silane, trichloro- Silicon chloride hydride (SiHCl3) trichlorosilane - silicochloroform 三氯硅烷 三氯硅烷; 三氯氢硅 trichlorosilane Trichloromonosilane Trichlorsilan Siliciumchloroform Silici-chloroforme Trichloorsilaan Trichlorosilane (HSiCl3) Triclorosilano Silane A-19 silicon chloroform
EC Number233-042-5
MDL NumberMFCD00011518
CAS Number10025-78-2
Merck Number9646
PubChem Substance ID87576354
Beilstein Registry Number2384789
Reaxys-RN2423756
Chemical Name Translation三氯硅烷
Wiswesser Line NotationG-SI-HGG
LabNetwork Molecule IDLN01806131
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分类

  • {SNA} Chemical Synthesis, Materials Science, Nanomaterials, POSS Precursors and Intermediates, Protecting and Derivatizing Reagents, Protection and Derivatization, RSiCl3, Silicon-Based, Silsesquioxanes: POSS Nanohybrids, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/35C4
  • Short: II/25A
  • Short: III/20b
  • Merck:14,9646

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
RTECSVV5950000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P231 Handle under inert gas. 在惰性气体中操作。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P335+P334
  • P370+P378
  • P403+P233
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupI
UN Number 1295 UN1295
Risk Statements
  • R12 Extremely flammable 极端易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
  • R35 Causes severe burns 会导致严重灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭,置于通风良好的场所;
Storage condition 0-10 Air & Moisture Sensitive 密封2-8°C保存 0-10°C
Hazard Codes 4.3 F+,C F+;C
Hazard Class4.3/3, 8
Warnings 危化品目录(2015)
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1 gm/m3
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Liver - fatty liver degeneration
   Blood - other changes
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 3,81,1961

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 2/21/1979

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1500 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,114,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1030 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information,

Restrict 危险品

其他信息

  • 水中分解,溶于苯、乙醚、正庚烷、氯仿、二硫化碳、四氯化碳和四氯乙烯。

系列性分类