2,2,2-trifluoroacetic trifluoromethanesulfonic anhydride 2,2,2-三氟乙酸三氟甲磺酸酐

CAS 68602-57-3 MFCD00011638

化学结构图

68602-57-3
SMILES: O=C(OS(=O)(=O)C(F)(F)F)C(F)(F)F

化学属性

Mol. FormulaC3
Mol. Weight246
Boiling Point62-63 °C(lit.)
Vapor Pressure400 mmHg ( 21.1 °C)

别名和识别编码

Chemical Name2,2,2-trifluoroacetic trifluoromethanesulfonic anhydride
CAS Number68602-57-3
Alfabeta NameTRIFLUOROACETYLTRIFLUOROMETHANESULFONATE
MDL NumberMFCD00011638
Synonym 三氟乙酰三氟甲磺酸酐 三氟乙酰基三氟甲磺酸酯 三氟乙酰三氟甲磺酸酐 三氟乙酰基三氟甲磺酸酯 三氟乙酰三氟甲磺酸酯 三氟乙酰基三氟甲磺酸酐
PubChem Substance ID87577290
Reaxys-RN794780
Chemical Name Translation2,2,2-三氟乙酸三氟甲磺酸酐
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Organic Building Blocks
  • Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • 1. J. Org. Chem. 52 , 4156, (1987)
  • Corp MSDS 1 (2), 3440:A / FT-IR 2 (1), 1524:D / FT-NMR 1 (1), 1445:C / RegBook 1 (1), 1071:J / Structure Index 1 , 166:A:8
  • Fieser 9 ,485 / Fieser 12 ,529

安全信息

Warnings MOISTURE SENSITIVE, CORROSIVE
WGK Germany3
Hazard Codes C T,C
Storage condition 0-10 0-10°C
UN Number 3265
Signal word Danger
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H301 Toxic if swallowed 吞食有毒
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P301+P310
  • P305+P351+P338
  • P304+P340
Hazard Class8
GHS Symbol
Packing GroupI
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R34 Causes burns 会导致灼伤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonates/Sulfinates - Sulfur Compounds

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