Acetonyltriphenylphosphonium Chloride 乙酰三苯基氯化鏻

CAS 1235-21-8 MFCD00011813

化学结构图

1235-21-8
SMILES: CC(=O)C[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Cl-]

化学属性

Mol. FormulaC21H20ClOP
Mol. Weight354.81
Melting Point243-245 °C
TSCANo
Stability对湿度敏感

别名和识别编码

Chemical NameAcetonyltriphenylphosphonium Chloride
Synonym (2-Oxopropyl)triphenylphosphonium chloride {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Oxopropyl)triphenylphosphonium
Beilstein Registry Number3922783
PubChem Substance ID196994
CAS Number1235-21-8
EC Number214-974-1
MDL NumberMFCD00011813
Reaxys-RN3922783
Chemical Name Translation乙酰三苯基氯化鏻
Wiswesser Line Notation1V1PR&R&R &G
InChIKeyXAMZZEBAJZJERT-UHFFFAOYSA-M
LabNetwork Molecule IDLN00222615
InChIInChI=1S/C21H20OP.ClH/c1-18(22)17-23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21;/h2-16H,17H2,1H3;1H/q+1;/p-1
Canonical SMILESO=C(C)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-]
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分类

  • {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • Beilstein:16(4)988

安全信息

WGK Germany3
RTECSTA1841000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P501a
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C Hygroscopic {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
GHS Symbol
Hazard Codes Xi 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01535

其他信息

  • TCI Shanghai:丙酮基三苯基氯化膦 Acetonyltriphenylphosphonium Chloride,>;98.0%(T)(1235-21-8)
  • Sigma Aldrich:1235-21-8(sigmaaldrich)
  • F:3
  • 图谱信息:乙酰三苯基氯化磷(1235-21-8)红外图谱(IR1) 乙酰三苯基氯化磷(1235-21-8)红外图谱(IR2) 乙酰三苯基氯化磷(1235-21-8)质谱(MS) 乙酰三苯基氯化磷(1235-21-8)核磁图( 13 CNMR)
  • Alfa Aesar:丙酮基三苯基氯化膦,99% Acetonyltriphenylphosphonium chloride, 99%(1235-21-8)
  • MOL 文件:1235-21-8.mol
  • 敏感性:Hygroscopic
  • Acros Organics:Acetonyltriphenylphosphonium chloride, 99%(1235-21-8)
  • 乙酰三苯基氯化磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1305 丙酮基三苯基氯化膦 Acetonyltriphenylphosphonium Chloride 25G 364元 2010/06/21 169630250 乙酰三苯基氯化磷 Acetonyltriphenylphosphonium chloride 99% 25 GR 713元 2010/05/25 A14691 丙酮基三苯基氯化膦, 99% Acetonyltriphenylphosphonium chloride, 99% 25g 364元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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