Bis(diisopropylamino)(2-cyanoethoxy)phosphine 双(二异丙基氨基)(2-氰基乙氧基)膦
CAS 102691-36-1 MFCD00012213
化学结构图
SMILES: CC(C)N(C(C)C)P(OCCC#N)N(C(C)C)C(C)C
化学属性
| Refractive index | 1.4680 to 1.4720 |
|---|---|
| Flash Point | 60°C(lit.) |
| Mol. Formula | C15H32N3OP |
| Mol. Weight | 301 |
| Density | 0.949 |
| Appearance | colorless liq. |
| Stability | moisture sensitive, store cold |
| Boiling Point | 100 |
别名和识别编码
| Chemical Name | Bis(diisopropylamino)(2-cyanoethoxy)phosphine |
|---|---|
| Synonym | 2-Cyanoethoxybis(N,N-diisopropylamino)phosphine 2-氰乙基N,N,N′,N′-四异丙基亚磷酰二胺 Bis(diisopropylamino)(2-cya Bis(diisopropylamino)(2-cyanoethoxy)phosphine N,N,N?,N?-Tetrakis(1-methylethyl)phosphorodiamidous Acid 2-Cyanoethyl Ester 双(二异丙基氨基)(2-氰乙氧基)膦 |
| PubChem Substance ID | 87560237 |
| Beilstein Registry Number | 3590103 |
| Reaxys-RN | 3590103 |
| EC Number | 250-023-7 |
| Chemical Name Translation | 双(二异丙基氨基)(2-氰基乙氧基)膦 |
| LabNetwork Molecule ID | LN00188898 |
| InChIKey | RKVHNYJPIXOHRW-UHFFFAOYSA-N |
| MDL Number | MFCD00012213 |
| CAS Number | 102691-36-1 |
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分类
- {SA} Building Blocks, Chemical Biology, Chemical Synthesis, Coupling Reagents, Nucleoside Chemistry, Organic Building Blocks, Phosphoramidites, Phosphorus Compounds
- Phosphorylating and Phosphitylating Agents
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphoramidites, Phosphorus
产品应用
- 用于合成亚磷酰化核苷酸的试剂
相关文献及参考
- 1. Bioconjug. Chem. 15 , 638-646, (2004) 摘要
- Bioorg. Med. Chem. 12 , 2843-2851, (2004) 摘要
- Bioorg. Med. Chem. 12 , 2385-2396, (2004) 摘要
- Corp MSDS 1 (1), 938:A / FT-IR 2 (1), 1551:B / FT-NMR 1 (1), 1469:C / RegBook 1 (1), 1095:H / Structure Index 1 , 169:A:6
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H319 Causes serious eye irritation 严重刺激眼睛
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P231+P232
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P342+P311
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P403+P235
- P422 Store contents under… 存储目录在…之下。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S3 Keep in a cool place 保存在阴凉处；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R42/43
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