Lithium Trifluoromethanesulfonate 三氟甲磺酸锂
CAS 33454-82-9 MFCD00013227
化学结构图
SMILES: O=S(=O)([O-])C(F)(F)F.[Li+]
化学属性
| Melting Point | >300 |
|---|---|
| TSCA | Yes |
| Density | 1.876 |
| Mol. Formula | CF3LiO3S |
| Mol. Weight | 156 |
| Appearance | white pwdr. |
| Stability | hygroscopic |
别名和识别编码
| Chemical Name | Lithium Trifluoromethanesulfonate |
|---|---|
| Synonym | LiTf LiTf 三氟甲基磺酸锂 三氟甲烷磺酸 锂盐 LiTf;三氟甲基磺酸锂;三氟甲烷磺酸 锂盐 Lithium triflate Lithium-Trifluormethansulfonat Lithiumtriflat (Lithiumtrifluormethansulfonat) Lithiumtrifluormethansulfonat Methanesulfonic acid, trifluoro-, lithium salt Trifluoromethanesulfonic Acid Lithium Salt, Lithium Triflate Trifluoromethanesulfonic acid, lithium salt Trifluoromethanesulphonic acid lithium salt lithium trifluoromethanesulfonate lithium trifluoromethanesulphonate 三氟甲基磺酸锂 三氟甲基磺酸锂 三氟甲烷磺酸 锂盐 三氟甲基磺酸锂;三氟甲烷磺酸;锂盐 三氟甲磺酸锂 |
| PubChem Substance ID | 87577307 |
| Beilstein Registry Number | 4301818 |
| EC Number | 251-528-5 |
| Chemical Name Translation | 三氟甲磺酸锂 |
| Reaxys-RN | 4301818 |
| MDL Number | MFCD00013227 |
| CAS Number | 33454-82-9 |
| LabNetwork Molecule ID | LN00220303 |
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分类
- {uni_hamburg} no charge; 2fragments
- {SNA} Chemical Synthesis, Inorganic Salts,
- {SNA} Alternative
- {SNA} Chemical Synthesis, Essential Chemicals, Inorganic Salts, Lithium, Lithium Salts, Metal and Ceramic Science, Research Essentials, Salts, Synthetic Reagents, 材料科学
- {SNA} Alternative Energy, Ch
相关文献及参考
- Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
- Catalyzes the aminolysis of epoxides in acetonitrile solution to give high yields of ß-amino alcohols, providing a safer substitute for Li perchlorate: Tetrahedron Lett., 37, 7715 (1996). Effective replacement for Li perchlorate as catalyst for Diels-Alder reactions: Synlett, 877 (2000).
- Efficient catalyst for chemoselective dithioacetalization of aldehydes, e.g. with 1,3-propanedithiol, under neutral, solvent-free conditions: Tetrahedron Lett., 40, 4055 (1999).
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S37 Wear suitable gloves 戴适当手套；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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