CAS 7440-36-0 MFCD00134030-Antimony 锑 -LabNovo

Antimony 锑

CAS 7440-36-0 MFCD00134030

化学结构图

SMILES: [Sb]

化学属性

Mol. Formula	Sb
Mol. Weight	121.76
Boiling Point	1635 °C(lit.)
Density	6.69 g/mL at 25 °C(lit.)
Melting Point	630 °C(lit.)
TSCA	Yes
Solubility	不溶
Flash Point	1380°C
Appearance	powder
Stability	对空气和湿度敏感

别名和识别编码

Chemical Name	Antimony
Synonym	锑粉/锑粒/高纯锑/锑标准溶液氯化锑(III) 溶液 Antimony bar Antimony, regulus 锑标液 Antimony Black Antimony black 锑 Stibium Antimony element 锑原子光谱标准浓缩液 1.00g Sb Antymon 锑标准浓缩液 10.00g Sb Antimony C.I. 77050 Sb (antimony) 锑标准溶液
MDL Number	MFCD00134030
PubChem Substance ID	5354495
CAS Number	7440-36-0
EC Number	231-146-5
Chemical Name Translation	锑
Merck Number	13,698
Wiswesser Line Notation	SB
LabNetwork Molecule ID	LN00193412
InChI	InChI=1S/Sb

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品牌质保精细包装现货库存一流品牌服务

产品应用

锑在冶金中主要用于制造合金；锑也用于半导体中；三氧化二锑还可作透明的珐琅质白颜料。也用于印刷和颜料行业。

安全信息

Personal Protective Equipment Gloves Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

WGK Germany2

GHS Symbol

Precautionary statements

P273 Avoid release to the environment. 避免释放到环境中。
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P304+P340+P310
P303+P361+P353

Signal word Danger Warning

Hazard statements

H332 Harmful if inhaled 吸入有害
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H302 Harmful if swallowed 吞食有害
H302+H332
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
H335 May cause respiratory irritation 可能导致呼吸道刺激

Hazard Codes Xn,N C N N,Xn,Xi Xn;N

RTECSCC4025000

Safety Statements

S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；

Packing GroupIII

UN Number UN1789 UN2871 2871 UN 3264 8/PG 2

Risk Statements

R34 Causes burns 会导致灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
R51/53
R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
R52/53
R37 Irritating to respiratory system 刺激呼吸道
R25 Toxic if swallowed 吞咽有毒
R20 Harmful by inhalation 吸入有害

Storage condition 充氩保存；塑料薄膜真空封装，防止受潮氧化。塑料薄膜真空封装，防止受潮氧化。充氩保存

Hazard Class6.1

Restrict 易制爆危险化学品

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/m3/7H/52W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 18,607,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,22,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 90 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,22,1982

其他信息

下游产品:三氧化二锑 --> 四氯化硅 --> 五氯化锑 --> 1,4-二氯苯 --> 锑酸钠 --> 硫化锑
{
用途六:主要用于制合金如印刷用的活字合金、硬质合金、巴氏合金。还用于制锑盐、医药、颜料及半导体材料等。用于I
锑价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 53206060 锑 100ml 40元 2011/08/23 53206062 锑 100ml 100元 2011/08/23 51002760 锑粒 25g 62元
Alfa Aesar:锑片,1-4mm(0.04-0.16in),99.9999%(metalsbasis) Antimony pieces, 5mm (0.2in) & down, 99.9999% (metals basis)(7
方法一:工业生产有蒸馏法和区域熔融法。蒸馏法将锑块加入反应器中，通入氯气进行氯化反应，生成三氯化锑。将粗品三氯化锑加入蒸馏器中，加入少量金属锑屑，经减压蒸馏除去五氯化锑及其杂质，然后在常压下蒸馏。取221～225℃之馏分，经冷却结晶，得到三氯化锑，经还原后，制得金属锑纯度≥99.999
类别:有毒物品
Sigma Aldrich:7440-36-0(sigmaaldrich)
Acros Organics:锑 Antimony, powder, 0.15 mm, 99+%(7440-36-0)
用途四:用于制造Ⅲ～V族化合物半导体、高纯合金、硫化锑。用作制冷元件和硅、锗单晶的掺杂剂等。
用途三:用作高纯试剂和半导体的原材料
职业标准:TWA 0.5 毫克(锑)/ 立方米; STEL 1.5 毫克(锑)/ 立方米
上游原料:三氧化二锑 --> 五氯化锑 --> 三氯化锑 --> 锑块
有两种同素异形体：黄色变体仅在-90C以下才稳定；金属变体是锑的稳定形式。2070°C时锑蒸汽为单原子分子。锑仅在赤热时与水反应放出氢气；高温时可与氧反应,生成三氧化二锑,为两性氧化物,难溶于水,但溶于酸和碱；可与浓硝酸反应。
灭火剂:干砂、干粉
储运特性:库房通风低温干燥; 与酸类、食品添加剂分开存放
爆炸物危险特性:粉尘遇明火爆炸
MSDS 信息:锑粉(7440-36
外观性质:银白色或深灰色金属粉末。
用途五:锑在冶金中主要用于制造合金；锑也用于半导体中；三氧化二锑还可作透明的珐琅质白颜料。也用于印刷和颜料行业。
参考质量标准:国家标准GB 10117—88 指标名称指标牌号Sb05 牌号Sb-06 外观呈银白色块状或粒状，产品表面应清洁，无氧化色斑高纯锑(Sb)/%≥ 99.999 99.9999 银(Ag)/(mg/kg)≤ 0.05 0.01 金(Au)/(mg/kg)≤ 0.2 0.05 镉(Cd)/(mg/kg)≤ 1.0 0.01 铜(Cu)/(mg/kg)≤ 0.05 0.01 铁(Fe)/(mg/kg)≤ 0.5 0.05 镁(Mg)/(mg/kg)≤ 0.2 0.05 镍(Ni)/(mg/kg)≤ 0.2 0.05 铅(Pb)/(mg/kg)≤ 0.5 0.05 锌(Zn)/(mg/kg)≤ 0.5 0.05 锰(Mn)/(mg/kg)≤ 0.05 0.01 砷(As)/(mg/kg)≤ 1.5 0.3 硫(S)/(mg/kg)≤ 0.5 0.1 硅(Si)/(mg/kg)≤ 1.0 0.1 铋(Bi)/(mg/kg)≤ 0.2 0.02
MOL 文件:7440-36-0.mol
毒性分级:高毒
可燃性危险特性:粉尘遇明火燃烧; 燃烧产生有毒锑化物烟雾; 与酸接触产生有毒SBH3气体
急性毒性:腹腔- 大鼠 LD50: 100 毫克/ 公斤; 腹腔- 小鼠 LD50: 80 毫克/ 公斤
MSDS 信息:锑粉(7440-36-0).msds