Oleoyl Chloride 油酰氯

CAS 112-77-6 MFCD00134332

化学结构图

112-77-6
SMILES: CCCCCCCC/C=C\CCCCCCCC(=O)Cl

化学属性

Mol. FormulaC18H33ClO
Mol. Weight301
Refractive index1.4570 to 1.4670
Boiling Point193 °C/4 mmHg(lit.)
Density0.91 g/mL at 25 °C(lit.)
Flash Point171°C(lit.)
Appearance 油酰氯(112-77-6)为液体。沸点200℃(1.46kPa),175-180℃(0.4kPa),相对密度0.912,折光率1.4623。
Stability对湿度敏感

别名和识别编码

Chemical NameOleoyl Chloride
CAS Number112-77-6
PubChem Substance ID5364783
EC Number204-005-0
Beilstein Registry Number1211748
MDL NumberMFCD00134332
Reaxys-RN1211748
Synonym 油酰氯 油醯氯 (Z)-9-Octadecenoylchloride oleoylchloride,(mixturewithca.35-40%elaidicacidchloride) (Z)-9-Octadecenoic acid chloride 9-OCTADECENOYL CHLORIDE 9-Octadecenoylchloride,(Z)- 油酸酰氯 Oleic chloride [(9Z)-1-Oxo-9-octadecenyl] chloride (z)-9-octadecenoylchlorid Oleoyl DELTA 9 CIS-OCTADECENOYL CHLORIDE OLEIC ACID CHLORIDE techn,mixturewithca.35-40%Elaidicacidchloride OCTADECENOYLCHLORIDE OLEOYL CHLORIDE, TECH., 85% 9-Octadecenoyl chloride, (9Z)- OLEOYL CHLORIDE
Chemical Name Translation油酰氯
LabNetwork Molecule IDLN01743492
InChIInChI=1S/C18H33ClO/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20/h9-10H,2-8,11-17H2,1H3/b10-9-
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分类

  • {SNA} Acid Chlorides, Biochemicals a
  • Acid Chlorides, Biochemicals and Reagents, Fatty Acids and conjugates, Fatty Acyls, Lipids, Monoenoic fatty acids, Others, Unsaturated Fatty Acids and Derivatives
  • {SNA} Acid Halides, Biochemicals and Reagents, Building Blocks, Carbonyl Compounds, Chemical Synthesis,
  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Fatty Acids and conjugates, Fatty Acyls, Monoenoic fatty acids, Organic Building Blocks, Other Monoenoic fatty acids, Unsaturated Fatty Acids and Derivatives, 生化试剂,

相关文献及参考

  • Beilstein: 2,IV,1668

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P305+P351+P338
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Signal word Danger {} {} {} {} {TCI}
UN Number UN 3265 8/PG 2 3265
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
Packing GroupII
Hazard Class8
Storage condition -20°C 充氩保存 0-10°C

其他信息

  • MOL 文件:112-77-6.mol
  • Sigma Aldrich:112-77-6(sigmaaldrich)
  • TCI Shanghai:油酰氯 Oleoyl Chloride,>;80.0%(GC)(112-77-6)
  • 用途一:用作有机合成中间体。用油酰氯将2-磺基-4-氨基苯甲醚旱灾行酰化反应可得净洗剂 LS(C25H40NNaO5S)。
  • 图谱信息:油酰氯(112-77-6)核磁图( 1 HNMR) 油酰氯(112-77-6)核磁图( 13 CNMR) 油酰氯(112-77-6)质谱(MS) 油酰氯(112-77-6)红外图谱(IR1)
  • 油酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 O0053 油酰氯 Oleoyl Chloride 25G 325元 2014/06/02 O0053 油酰氯 Oleoyl Chloride 250G 1290元
  • 上游原料:三氯化磷
  • 方法一:由油酸与三氯化磷反应而得。将油酸投入反应锅,在搅拌下缓缓加入三氯化磷,加料温度控制在25-33℃。加毕,升温到55℃,保温4h后分去下层亚磷酸,即得油酰氯。
  • 油酰氯是一种脂肪酸衍生物。

系列性分类


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