Dichloro(Dimethylamino)Phosphine 二氯(二甲氨基)膦

CAS 683-85-2 MFCD00013613

化学结构图

683-85-2
SMILES: CN(C)P(Cl)Cl

化学属性

Mol. FormulaC2H6Cl2NP
Mol. Weight145.95 g/mol
Density1.271 g/mL at 25 °C(lit.)
Flash Point-23°C(lit.)
TSCANo
Boiling Point150 °C(lit.)
Refractive indexn20/D 1.505(lit.)

别名和识别编码

Chemical NameDichloro(Dimethylamino)Phosphine
Synonym (CH3)2NPCl2 (DIMETHYLAMINO)PHOSPHONOUS DICHLORIDE (Dimethylamino)dichlorophosphine DICHLORO(DIMETHYLAMINO)PHOSPHINE DIMETHYLAMINODICHLOROPHOSPHINE DIMETHYLAMINOPHOSPHOROUS DICHLORIDE DIMETHYLAMINOPHOSPHORUS DICHLORIDE DIMETHYLPHOSPHORAMIDOUS DICHLORIDE Dichlor(dimethylamino)phosphan Dichloro(dimethylamino)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00013613
CAS Number683-85-2
PubChem Substance ID136483
Chemical Name Translation二氯(二甲氨基)膦
Reaxys-RN1733157
Beilstein Registry Number4(4)274
InChIKeyXPWWDZRSNFSLRQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN01744058
InChIInChI=1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Phosphorus Halides

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Packing GroupII
UN Number UN2924 2924 UN 2924 3/PG 2
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
Storage condition Moisture Sensitive 0-10 0-10°C Refrigerator (+4°C) + Flammables area
GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P403+P235
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P301+P330+P331
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P303+P361+P353
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
Signal word Danger
Hazard Codes F,C
Hazard Class3/8

其他信息

  • TCI Shanghai:二氯化(二甲氨基)膦 Dichloro(dimethylamino)phosphine,>;98.0%(GC)(683-85-2)
  • MOL 文件:683-85-2.mol
  • Alfa Aesar:二氯二甲氨基膦,98% Dichloro(dimethylamino)phosphine, 98%(683-85-2)
  • 二甲基氯化磷胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3245 二氯(二甲氨基)膦 Dichloro(dimethylamino)phosphine 5G 857元 2010/06/21 383350250 二甲基氯化磷胺 Dimethylphosphoramidous dichloride 97% 25 ML 2084元 2010/06/21 383350050 二甲基氯化磷胺 Dimethylphosphoramidous dichloride 97% 5 ML 603元
  • Sigma Aldrich:683-85-2(sigmaaldrich)
  • 敏感性:Moisture Sensitive
  • Acros Organics:二甲基氯化磷胺 Dimethylphosphoramidous dichloride(683-85-2)

系列性分类


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