Bis(diethylamino)?chlorophosphine 双（二乙氨基）氯膦

CAS 685-83-6 MFCD00015493

化学结构图

685-83-6
SMILES: CCN(CC)P(Cl)N(CC)CC

化学属性

Refractive indexn20/D 1.4895(lit.)
Flash Point101°(214°F)
TSCANo
Mol. FormulaC8H20ClN2P
Mol. Weight211
Density1.002
Appearance colorless to light yellow liq. (may contain trace insolubles)
Stabilityair sensitive, moisture sensitive
Boiling Point124-125°C/15 mm

别名和识别编码

Chemical NameBis(diethylamino)?chlorophosphine
Synonym AURORA KA-1225 BDAPCD BIS(DIETHYLAMINO)CHLOROPHOSPHINE Bis(diethylamino)chlorophosphine Bis(diethylamino)chlorophosphine, min. 97% Bis(diethylamino)chlorophosphine,min.97% Bis(diethylamino)chlorphosphine Bis(diethylamino)phosphorochloridite Bis(diethylamino)phosphorochloriditeChlorobis(diethylamino)phosphine Bis-(diethylamino)-chlorphosphin N,N,N',N'-Tetraethylphosphorodiamidous chloride bis(diethylamino)phosphorchloridite bis(diethylamino)phosphorochloridite chlorobis(diethylamino)phosphine tetraethyldiamidophosphorous acid chloride tetraethyldiamidophosphorousacidchloride tetraethylphosphorodiamidous chloride tetraethylphosphorodiamidouschloride 双(二乙基氨基)氯膦 双(二乙胺基)氯磷
EC Number250-023-7
Beilstein Registry Number2384789
PubChem Substance ID2733351
Chemical Name Translation双（二乙氨基）氯膦
LabNetwork Molecule IDLN01871742
InChIKeyJVEHJSIFWIIFHM-UHFFFAOYSA-N
MDL NumberMFCD00015493
CAS Number685-83-6
InChIInChI=1S/C8H20ClN2P/c1-5-10(6-2)12(9)11(7-3)8-4/h5-8H2,1-4H3
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors

相关文献及参考

  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number UN3265 3265 UN 3265 8/PG 2
Storage condition Air & Moisture Sensitive
Hazard Codes C
Hazard Class8
Restrict 危险品

其他信息

  • Sigma Aldrich:685-83-6(sigmaaldrich)
  • Acros Organics:双（二乙胺基）氯磷 Bis(diethylamino)chlorophosphine, 97%(685-83-6)
  • 双(二乙胺基)氯磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 317360010 双(二乙胺基)氯磷 Bis(diethylamino)chlorophosphine 97% 1 GR 358元 2010/05/25 B21019 双(二乙基氨基)氯膦, 94% Bis(diethylamino)chlorophosphine, 94% 5g 1652元 2010/05/25 B21019 双(二乙基氨基)氯膦, 94% Bis(diethylamino)chlorophosphine, 94% 25g 6552元
  • 上游原料:正己烷 --> 三氯化磷 --> 二乙胺
  • MOL 文件:685-83-6.mol
  • 敏感性:Air & Moisture Sensitive
  • Alfa Aesar:双(二乙基氨基)氯膦,94% Bis(diethylamino)chlorophosphine, 94%(685-83-6)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Phosphite Ligands
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  3. Aminophosphines

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