Bis(2-Diphenylphosphinophenyl)Ether 双(2-二苯基磷苯基)醚

CAS 166330-10-5 MFCD00233863

化学结构图

166330-10-5
SMILES: c1ccc(P(c2ccccc2)c2ccccc2Oc2ccccc2P(c2ccccc2)c2ccccc2)cc1

化学属性

TSCANo
Density1.422
Mol. FormulaC36H28OP2
Mol. Weight539
Appearance off-white pwdr.
Melting Point184-187

别名和识别编码

Chemical NameBis(2-Diphenylphosphinophenyl)Ether
Synonym 双[(2-二苯膦基)苯基]醚 DPEPhos 双[(2-二苯膦基)苯基]醚 DPEphos 双(2-二苯基磷苯基)醚 DPEPhos
PubChem Substance ID87558783
EC Number000-000-0
Beilstein Registry Number7729718
Reaxys-RN7729718
Chemical Name Translation双(2-二苯基磷苯基)醚
LabNetwork Molecule IDLN00155010
MDL NumberMFCD00233863
CAS Number166330-10-5
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands
  • {SNA} 12 Principles Aligned Products, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Greener Alternative Products, Phosphine Compounds, Polydentate Phosphine Ligands

产品应用

  • 膦配体

相关文献及参考

  • Bidentate ligand, investigated in Rh-catalyzed regioselective hydroformylation of olefins: Organometallics, 14, 3081 (1995). Reported by Buchwald to be highly effective in promoting the Pd-catalyzed N-arylation of anilines: Tetrahedron Lett., 39, 5327 (1998).

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Signal word Warning
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Polydentate Phosphine Ligands 多齿膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Phosphorus Precursors
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Ligands
  2. 96-1650 Phosphine Ligand Kit for Palladium-Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond Formation
  1. Phosphine
  2. 96-1650 Phosphine Ligand Kit for Palladium-Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond Formation
  1. Pincer Ligands and Complexes
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  3. Bridged Phosphine Ligands

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