2-Bromo-2’-Fluoroacetophenone 2-溴-2’-氟苯乙酮

CAS 655-15-2 MFCD00278796

化学结构图

655-15-2
SMILES: O=C(CBr)c1ccccc1F

化学属性

Mol. FormulaC8H6BrFO
Mol. Weight217.04
Boiling Point239.4°C at 760 mmHg
Melting Point25-27°C
Density1.574 g/mL at 25 °C
Refractive indexn20/D 1.563
TSCANo
Flash Point>110°C

别名和识别编码

Chemical Name2-Bromo-2’-Fluoroacetophenone
CAS Number655-15-2
Alfabeta NameBROMOFLUOROACETOPHENONE 22---'
MDL NumberMFCD00278796
Synonym 2-Bromo-2'-fluoroacetophenone {LY} 2-Bromo-2'-fluoroacetophenone {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacetophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-2'-fluoroacet
Chemical Name Translation2-溴-2’-氟苯乙酮
PubChem Substance ID329766780
LabNetwork Molecule IDLN00116130
Reaxys-RN2083115
Canonical SMILESBrCC(C1=CC=CC=C1F)=O
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分类

  • {SNA} Acid Halides, Aryl Fluorinated Building Blocks, Building Blocks, C7-C8, Carbonyl Compounds, Chemical Synthesis, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • {SNA} Acid Halides, Aryl Fluorinated Building Blocks, Building Blocks, C7, C8-C12, Carbonyl Compounds, Chemical Synthesis, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • Aromatics

产品应用

  • A new class of acetophenone-based cinchona alkaloid-derived quaternary ammonium salts were prepared and evaluated as phase-transfer catalysts in the enantioselective alkylation of glycine imine ester.

相关文献及参考

  • Sheehan, S., et al.: Bioorg. Med. Chem. Lett., 17, 1765 (2007),

安全信息

Warnings LACHRYMATOR, CORROSIVE
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
WGK Germany3
GHS Symbol
Precautionary statements
  • P303+P361+P353+P310+P363
  • P305+P351+P338
  • P304+P340+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P301+P330+P331+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Signal word Danger
Hazard Codes C
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R34 Causes burns 会导致灼伤
Packing GroupIII
UN Number UN3265 3261
Storage condition 2-8°C {LY} 2-8°C Keep Cold {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Class8

其他信息

  • 敏感性:Lachrymatory
  • 下游产品:3-(2-氟苯基)-5-氨基异噁唑
  • MOL 文件:655-15-2.mol
  • Hazard Note:Corrosive/Lachrymatory/Keep Cold

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C7 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)

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