Methyl 4-(bromomethyl)benzoate 4-溴甲基苯甲酸甲酯

CAS 2417-72-3 MFCD00032453

化学结构图

2417-72-3
SMILES: COC(=O)c1ccc(CBr)cc1

化学属性

Mol. FormulaC9H9BrO2
Mol. Weight229.07
Density1.470
Boiling Point309.7°C at 760 mmHg
Melting Point57-58°C
TSCANo
Flash Point127.8±22.6 °C

别名和识别编码

Chemical NameMethyl 4-(bromomethyl)benzoate
CAS Number2417-72-3
Alfabeta NameMETHYLBROMOMETHYLBENZOATE 4()-
MDL NumberMFCD00032453
Synonym p-(Methoxycarbonyl)benzyl bromide {LY} p-(Methoxycarbonyl)benzyl bromide {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)benzyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-(Methoxycarbonyl)ben
EC Number000-000-0
Beilstein Registry Number1867272
PubChem Substance ID256687
Reaxys-RN1867272
Chemical Name Translation4-溴甲基苯甲酸甲酯
LabNetwork Molecule IDLN00008287
InChIInChI=1S/C9H9BrO2/c1-12-9(11)8-4-2-7(6-10)3-5-8/h2-5H,6H2,1H3
Canonical SMILESO=C(C1=CC=C(C=C1)CBr)OC
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分类

  • Intermediates
  • Aromatics
  • Catalyst
  • {SNA} Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

产品应用

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相关文献及参考

  • Cushman, M. et al.: Bioorg. Med. Chem. Lett., 8, 833 (1998); Nagao, Y. et al.: Chem. Pharmac. Bull., 36, 509 (1988);

安全信息

Warnings IRRITANT
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
  • P301+P310
  • P301+P316
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P341
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P342+P311
  • P342+P316
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H301 Toxic if swallowed 吞食有毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupIII
UN Number 3261 UN 3261 8/PG 2
Hazard Codes 8 C
Hazard Class8
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 图谱信息:4-溴甲基苯甲酸甲酯(2417-72-3)核磁图( 13 CNMR) 4-溴甲基苯甲酸甲酯(2417-72-3)核磁图( 1 HNMR)
  • 下游产品:依普罗沙坦
  • MSDS 信息:Methyl 4-(bromomethyl)benzoate(2417-72-3).msds
  • 4-溴甲基苯甲酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2053 4-(溴甲基)苯甲酸甲酯 Methyl 4-(Bromomethyl)benzoate 10G 502元 2014/06/02 B2053 4-(溴甲基)苯甲酸甲酯 Methyl 4-(Bromomethyl)benzoate 25G 987元 2010/06/21 306100250 4-溴甲基苯甲酸甲酯 Methyl 4-(bromomethyl)benzoate 98% 25 GR 1437元
  • Acros Organics:4-溴甲基苯甲酸甲酯 Methyl 4-(bromomethyl)benzoate, 98%(2417-72-3)
  • MOL 文件:2417-72-3.mol
  • 敏感性:Lachrymatory
  • Hazard Note:Irritant
  • Sigma Aldrich:2417-72-3(sigmaaldrich)
  • Alfa Aesar:4-(溴甲基)苯甲酸甲酯,98% Methyl 4-(bromomethyl)benzoate, 98%(2417-72-3)
  • TCI Shanghai:4-溴甲基苯甲酸甲酯 Methyl 4-(Bromomethyl)benzoate,>;97.0%(GC)(2417-72-3)

系列性分类


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