2-Bromo-6-Methoxynaphthalene 2-溴-6-甲氧基萘

CAS 5111-65-9 MFCD00004062

化学结构图

5111-65-9
SMILES: COc1ccc2cc(Br)ccc2c1

化学属性

Mol. FormulaC11H9BrO
Mol. Weight237.09
Density1.422
Melting Point106-109°C
TSCANo
Boiling Point324.7°C at 760 mmHg
Flash Point160-164°C/3mm

别名和识别编码

Chemical Name2-Bromo-6-Methoxynaphthalene
CAS Number5111-65-9
Alfabeta NameBROMOMETHOXYNAPHTHALENE 26---
MDL NumberMFCD00004062
Synonym 2-Bromo-6-methoxynaphthalene {LY} 2-Bromo-6-methoxynaphthalene {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-6-methoxynaphthalene {} {} {}
EC Number225-837-0
Beilstein Registry Number2043874
PubChem Substance ID78786
Reaxys-RN2043874
Chemical Name Translation2-溴-6-甲氧基萘
LabNetwork Molecule IDLN00009731
InChIInChI=1S/C11H9BrO/c1-13-11-5-3-8-6-10(12)4-2-9(8)7-11/h2-7H,1H3
Canonical SMILESCOC1=CC2=CC=C(Br)C=C2C=C1
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分类

  • Impurities
  • {SNA} Building Blocks, C11, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • Pharmaceuticals
  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; ether; 1fragment
  • Intermediates & Fine Chemicals
  • Aromatics

产品应用

  • Naproxen Impurity N.

相关文献及参考

  • Short: III/35D2
  • Undergoes highly efficient, phosphine-free Suzuki coupling reactions with arylboronic acids in water, catalyzed by Pd(II) acetate in the presence of TBAB and potassium carbonate: J. Org. Chem., 62, 7170 (1997).
  • Short: IV/7a
  • Markku, A., et al.: J. Pharm. Sci., 66, 433 (1977),

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P317
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P319
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn Xi
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • Sigma Aldrich:5111-65-9(sigmaaldrich)
  • Alfa Aesar:2-溴-6-甲氧基萘,98% 2-Bromo-6-methoxynaphthalene, 98%(5111-65-9)
  • 下游产品:4-(6-甲氧基-2-萘基)-3-丁烯-2-酮
  • 方法一:用2-溴-6-萘酚以硫酸二甲酯甲基化制得。
  • 图谱信息:2-溴-6-甲氧基萘(5111-65-9)质谱(MS) 2-溴-6-甲氧基萘(5111-65-9)红外图谱(IR2) 2-溴-6-甲氧基萘(5111-65-9)核磁图( 13 CNMR) 2-溴-6-甲氧基萘(5111-65-9)核磁图( 1 HNMR) 2-溴-6-甲氧基萘(5111-65-9)红外图谱(IR1)
  • 2-溴-6-甲氧基萘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1547 2-溴-6-甲氧基萘 2-Bromo-6-methoxynaphthalene 25G 623元 2014/06/02 B1547 2-溴-6-甲氧基萘 2-Bromo-6-methoxynaphthalene 250G 3100元 2010/06/21 190560250 2-溴-6-甲氧基萘 2-Bromo-6-methoxynaphthalene 98% 25 GR 2113元
  • MSDS 信息:2-Bromo-6-methoxynaphthalene(5111-65-9).msds
  • Acros Organics:2-溴-6-甲氧基萘 2-Bromo-6-methoxynaphthalene, 98%(5111-65-9)
  • 用途一:用作萘普生等药物中间体
  • TCI Shanghai:2-溴-6-甲氧基萘 2-Bromo-6-methoxynaphthalene,>;98.0%(GC)(5111-65-9)
  • 用途二:萘丁美酮的中间体。
  • MOL 文件:5111-65-9.mol

系列性分类


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