Silver Diethyldithiocarbamate 二乙基二硫代氨基甲酸银

CAS 1470-61-7 MFCD00004929

化学结构图

1470-61-7
SMILES: CCN(CC)C(=S)S[Ag]

化学属性

Mol. FormulaC5H10AgNS2
Mol. Weight256.14
Melting Point172-175 °C
TSCAYes
Density1.422
Stability对光敏感

别名和识别编码

Chemical NameSilver Diethyldithiocarbamate
MDL NumberMFCD00004929
CAS Number1470-61-7
EC Number216-003-7
Synonym Silver diethyldithiocarbamate {LY} Silver diethyldithiocarbamate {} {LY} Silver diethyldithiocarbamate {} {} {LY} Silver diethyldithiocarbamate {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number3718150
PubChem Substance ID3034078
Reaxys-RN3718150
Chemical Name Translation二乙基二硫代氨基甲酸银
InChIInChI=1S/C5H11NS2.Ag/c1-3-6(4-2)5(7)8;/h3-4H2,1-2H3,(H,7,8);/q;+1/p-1
LabNetwork Molecule IDLN00193703
Canonical SMILESCCN(CC)C(S[Ag])=S
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分类

  • {SNA} Analytical Reagents for General Use, Electron Spin Resonance (ESR/EPR) Spectroscopy, Essential Chemicals, Puriss p.a. ACS, Q-S, Puriss p.a. ACS, Research Essentials, Salts, Silver Salts,
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Research Essentials, Salts,

产品应用

  • 用作光度法测定微量砷的显色剂。也用于锑的光度测定。
  • 和Fe2+结合检测大脑、肾、肝和其它组织中的NO,同时直接测量NO和 pO2 ;作为铜的螯合剂,还用于依靠ESR定量分析生物材料里的铜;砷试剂也是超氧化物歧化酶, 抗坏血酸氧化酶和其它酶的抑制剂。抑制巨噬细胞NO合成酶

相关文献及参考

  • Beilstein:4,121

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P317
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Hazard Codes Xi

其他信息

  • 对湿空气和光敏感。不溶于水。易溶于吡啶和三氯甲烷,难溶于乙醇、丙醇和苯。在一定条件下,与砷化氢反应形成红色产物。
  • 用途二:用作光度法测定微量砷的显色剂。也用于锑的光度测定。和Fe2+结合检测大脑、肾、肝和其它组织中的NO,同时直接测量NO和 pO2 ;作为铜的螯合剂,还用于依靠ESR定量分析生物材料里的铜;砷试剂也是超氧化物歧化酶, 抗坏血酸氧化酶和其它酶的抑制剂。抑制巨噬细胞NO合成酶
  • F:8
  • Acros Organics:二乙基二硫代氨基甲酸银 Diethyldithiocarbamic acid, silver salt, p.a., 99%(1470-61-7)
  • MOL 文件:1470-61-7.mol
  • Sigma Aldrich:1470-61-7(sigmaaldrich)
  • 用途一:用作测砷试剂
  • 二乙基二硫代氨基甲酸银价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30058362 二乙基二硫代氨基甲酸银盐;二乙氨基二硫代甲酸银; 砷试剂 5g 30元 2011/08/23 30058363 二乙基二硫代氨基甲酸银盐;二乙氨基二硫代甲酸银; 砷试剂 5g 30元 2011/08/23 30058361 二乙基二硫代氨基甲酸银盐;二乙氨基二硫代甲酸银; 砷试剂 5g 46元
  • TCI Shanghai:二乙基二硫代氨基甲酸银[用于分析砷] Silver N,N-Diethyldithiocarbamate [for As analysis],>;98.0%(T)(1470-61-7)
  • 外观性质:浅黄色结晶性粉末。对湿空气和光敏感。不溶于水。易溶于吡啶和三氯甲烷,难溶于乙醇、丙醇和苯。在一定条件下,与砷化氢反应形成红色产物。熔点:172-175℃
  • Alfa Aesar:二乙基二硫代氨基甲酸银,ACS Silver diethyldithiocarbamate, ACS(1470-61-7)
  • TSCA:Yes

系列性分类