Hydrazine sulfate 硫酸肼
CAS 10034-93-2 MFCD00044873
化学结构图
SMILES: NN.O=S(=O)(O)O
化学属性
| Mol. Formula | H2NNH2 |
|---|---|
| Mol. Weight | 130 |
| Melting Point | 254 |
| Density | 1.370 |
| TSCA | Yes |
| Solubility | 溶于水，不溶于乙醇、乙醚，易溶于热水。 |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | Hydrazine sulfate |
|---|---|
| CAS Number | 10034-93-2 |
| PubChem Substance ID | 24852935 |
| EC Number | 233-110-4 |
| Beilstein Registry Number | 8778859 |
| MDL Number | MFCD00044873 |
| Merck Number | 14,4772 |
| Synonym | Hydrazine dihydrogen sulfate (salt) 硫酸联氨 Hydrazinium sulfate 肼 硫酸盐 硫酸肼 硫酸联铵 hydrazinium(2+) sulphate Hydrazin Sulfat Hydrazine dihydrogen sulfate salt Hydrazinium(2+) sulfate NSC-150014 Hydrazinsulfat (1:1) Hydrazine sulphate Hydrazine, sulfate (1:1) Hydrazine monosulfate 硫酸肼; 硫酸联铵; 肼硫酸盐 HS Hydrazine hydrogen sulfate Sehydrin Segidrin Hydraziniumsulfat Hydrazoniumsulfat Hydrazine sulfate (1:1) Hydrazonium sulfate hydrazine sulphate (1:1) |
| Chemical Name Translation | 硫酸肼 |
| LabNetwork Molecule ID | LN00194232 |
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分类
- {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography,
- Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Building Blocks, Chemical Synthesis, E-H, Puriss p.a., Hydrazines, Nitrogen Compounds, Organic Building Blocks, Puriss p.a.
- {SN
产品应用
- 重量测定镍、钴和镉，提纯稀有金属，还原剂，有机合成，分离钋与碲，测定氯酸盐、次氯酸和羧基化合物，肝功能试验中制备麝香草酚浊度液。
- 工业上用于制异烟肼、呋喃西林、百生肼、无水肼、杀虫剂和杀菌剂等，用于火箭燃料处理、防锈产品中，制造ADC发泡剂。广泛用于医药, 有机合成, 农药, 塑料, 橡胶等工业;
相关文献及参考
- Short: III/20a
- Short: III/31a
- Merck:14,4772
- Reagent for determination of C-terminal amino acid in peptides: Biochem. J ., 68, 475 (1958).
安全信息
GHS Symbol
- H331 Toxic if inhaled 吸入中毒
- H311 Toxic in contact with skin 皮肤接触中毒
- H301 Toxic if swallowed 吞食有毒
- H350 May cause cancer 可能致癌
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H301+H311+H331
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P305+P351+P338
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R35 Causes severe burns 会导致严重灼伤
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R45 May cause cancer 可能致癌
- R50/53
其他信息
- 易溶于热水，微溶于冷水；水溶液呈酸性，不溶于乙醇和乙醚，在空气中很稳定，易受碱和氧化剂作用。吸湿性弱，有强烈还原作用。
- Hydrazinium sulfate is a useful agent for the N-deacylation of various molecules. In the N-deacylation of the ceramide moiety of glycosphingolipids, Hydrazine sulfate was an effective catalyst for the deacylation of the ceramide moiety. It has been used in a modified hydrazinolysis procedure in which the glycosaminoglycans were heated with a hydrazine solution resulting in rapid rates of N-deacetylation and minimal conversion of uronic acid residues to their hydrazide derivatives.
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