Tert-Butyl 2-Bromo-2-Methylpropionate 2-溴-2-甲基丙酸叔丁酯
CAS 23877-12-5 MFCD00051908
化学结构图
SMILES: CC(C)(C)OC(=O)C(C)(C)Br
化学属性
| Mol. Formula | C8H15BrO2 |
|---|---|
| Mol. Weight | 223 |
| Density | 1.180 |
| Refractive index | 1.4350 to 1.4390 |
| TSCA | No |
| Boiling Point | 37°C/1mmHg(lit.) |
别名和识别编码
| Chemical Name | Tert-Butyl 2-Bromo-2-Methylpropionate |
|---|---|
| Synonym | Propanoic acid, 2-bromo-2-methyl-, 1,1-dimethylethyl ester 2-Bromo-2-methyl-propionic acid tert-butyl ester 2-Bromoisobutyric acid tert-butyl ester 2-溴-2-甲基丙酸叔丁酯 tert-Butyl 2-bromoisobutyrate 2-Bromoisobutyric acid tert-butyl estertert-Butyl 2-methyl-2-propionate tert-butyl α-bromoisobutyrate 2-溴代异丁酸叔丁酯 tert-butyl 2-bromo-2-methylpropionate tert-Butyl 2-bromo-2-methylpropionate; 2-Bromoisobutyric acid tert-butyl ester α-溴异丁酸叔丁酯 |
| MDL Number | MFCD00051908 |
| EC Number | 245-924-7 |
| CAS Number | 23877-12-5 |
| Beilstein Registry Number | 1905654 |
| PubChem Substance ID | 87561434 |
| Reaxys-RN | 1905654 |
| Chemical Name Translation | 2-溴-2-甲基丙酸叔丁酯 |
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分类
- {uni_hamburg} no charge; ester; 1fragment
- {SNA} ATRP, ATRP Initiators, Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, 材料科学
- {SNA} ATRP, ATRP Initiators, Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Materials Science, Organic Building Blocks, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization
相关文献及参考
- Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P302+P352+P332+P313+P362+P364
- P403+P235
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
- H227 Combustible liquid 可燃液体
GHS Symbol
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