4-Methylpiperidine 4-甲基哌啶

CAS 626-58-4 MFCD00006005

化学结构图

626-58-4
SMILES: CC1CCNCC1

化学属性

Mol. FormulaC6H13N
Mol. Weight99
Density0.838
Refractive index1.4440 to 1.4490
Flash Point9°C(lit.)
TSCAYes
Boiling Point122-126
Melting Point4-5°
SolubilityMISCIBLE
Danger-Level甲类

别名和识别编码

Chemical Name4-Methylpiperidine
MDL NumberMFCD00006005
CAS Number626-58-4
EC Number210-954-1
Beilstein Registry Number1083
Synonym γ-甲基哌啶 4-哌可啉 -Pipecoline,4-Pipecoline 3-Pipecoline; Hexahydro-3-picoline 4-METHYLPIPERIDINE 4-Methylpiperidine, 98+% 4-Methylpiperidine99% 4-PIPECOLINE 4-METHYL PIPERIDINE 4-Pipecoline 4-methyl-piperidin 4-methylpiperidine 4-甲基六氢吡啶 4-甲基哌啶 4-甲基哌啶, 98+% 4Me-Pip AKOS BBS-00003666 GAMMA-PIPECOLINE HEXAHYDRO-G-PICOLINE PIPECOLINE = 4-METHYLPIPERIDINE Piperidine, 4-methyl- g-Pipecoline γ-Pipecoline, 4-Pipecoline γ-Pipecoline,4-Pipecoline
PubChem Substance ID69381
Chemical Name Translation4-甲基哌啶
Reaxys-RN1083
InChIKeyUZOFELREXGAFOI-UHFFFAOYSA-N
LabNetwork Molecule IDLN00221277
InChIInChI=1S/C6H13N/c1-6-2-4-7-5-3-6/h6-7H,2-5H2,1H3
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分类

  • {SNA} Building Blocks, C5 to C7, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R11 Highly flammable 非常易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupII
UN Number 1993 2924 UN2733
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 F;Xi
Hazard Class3
Storage condition Flammables area
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • TCI Shanghai:4-甲基哌啶 4-Pipecoline,>;98.0%(GC)(T)(626-58-4)
  • 用途一:用于有机合成
  • 下游产品:
  • Sigma Aldrich:626-58-4(sigmaaldrich)
  • Alfa Aesar:4-甲基哌啶,98+% 4-Methylpiperidine, 98+%(626-58-4)
  • Acros Organics:4-甲基哌啶 4-Methylpiperidine, 99%(626-58-4)
  • 图谱信息:4-甲基六氢吡啶(626-58-4)核磁图( 13 CNMR) 4-甲基六氢吡啶(626-58-4)红外图谱(IR1) 4-甲基六氢吡啶(626-58-4)核磁图( 1 HNMR) 4-甲基六氢吡啶(626-58-4)红外图谱(IR2) 4-甲基六氢吡啶(626-58-4)质谱(MS)
  • MSDS 信息:4-甲基六氢吡啶(626-58-4).msds
  • MOL 文件:626-58-4.mol
  • 外观性质:无色液体。
  • 海关编码:29333999
  • 4-甲基六氢吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0445 4-甲基哌啶 4-Pipecoline 25ML 137元 2014/06/02 P0445 4-甲基哌啶 4-Pipecoline 500ML 735元 2010/06/21 127511000 4-甲基六氢吡啶 4-Methylpiperidine 99% 100 GR 312元

系列性分类