N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine N-(甲氧甲基)-N-(三甲基硅甲基)苄胺

CAS 93102-05-7 MFCD00674005

化学结构图

93102-05-7
SMILES: COCN(Cc1ccccc1)C[Si](C)(C)C

化学属性

Mol. FormulaC13H23NOSi
Mol. Weight237.41
Density0.928
Refractive index1.4890 to 1.4940
Flash Point104.2±21.8 °C
TSCANo
Boiling Point76°C at 0.3 mmHg

别名和识别编码

Chemical NameN-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
CAS Number93102-05-7
Alfabeta NameMETHOXYMETHYLTRIMETHYLSILYLMETHYLBENZYLAMINE NN(())----
MDL NumberMFCD00674005
EC Number000-000-0
Beilstein Registry Number4311216
PubChem Substance ID87564822
Synonym N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {} {} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine {} {} {} {} {} {} {}
Reaxys-RN4311216
Chemical Name TranslationN-(甲氧甲基)-N-(三甲基硅甲基)苄胺
LabNetwork Molecule IDLN00009631
InChIInChI=1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3
Canonical SMILESCOCN(C[Si](C)(C)C)CC1=CC=CC=C1
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分类

  • {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents

相关文献及参考

  • Ultrasound treatment with LiF in acetonitrile generates an azomethine ylide which undergoes 1,3-dipolar cycloaddition to olefins to give pyrrolidine derivatives in good yield: J. Org. Chem., 52, 235 (1987). Also found use in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds: J. Org. Chem., 66, 2526 (2001).

安全信息

Warnings IRRITANT
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Storage condition -20°C, sealed storage, away from moisture and light {LY} -20°C, sealed storage, away from moisture and light Moisture & Light Sensitive Store at room temperature {} {LY} -20°C, sealed storage, away from moisture and light {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from
WGK Germany3
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
GHS Symbol
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Silicon-Based - Protecting and Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Functional Group 官能团索引
  2. hemiaminal

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