2-Hydroxymethyl-1,4-benzodioxane (2,3-二氢苯并[b][1,4]二氧杂环己烯-2-基)甲醇

CAS 3663-82-9 MFCD00006822

化学结构图

3663-82-9
SMILES: OCC1COc2ccccc2O1

化学属性

Mol. FormulaC9H10O3
Mol. Weight166.18
Melting Point87-90°C
TSCANo
Boiling Point286°C at 760 mmHg

别名和识别编码

Chemical Name2-Hydroxymethyl-1,4-benzodioxane
CAS Number3663-82-9
Alfabeta NameDIHYDROBENZODIOXINYLMETHANOL 23142[]()-----,,
MDL NumberMFCD00006822
Synonym (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {} {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {} {} {} {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {} {} {} {} {} {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanol {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2,3-Dihydrobenzo[b][1,4]di
PubChem Substance ID19314
EC Number222-921-9
Reaxys-RN83736
Beilstein Registry Number83736
Chemical Name Translation(2,3-二氢苯并[b][1,4]二氧杂环己烯-2-基)甲醇
InChIKeyGWQOQQVKVOOHTI-UHFFFAOYSA-N
Wiswesser Line NotationT66 BO EOT&J C1Q
LabNetwork Molecule IDLN00158473
Canonical SMILESOCC1COC2=C(O1)C=CC=C2
InChIInChI=1S/C9H10O3/c10-5-7-6-11-8-3-1-2-4-9(8)12-7/h1-4,7,10H,5-6H2
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分类

  • Alcohols, Benzodioxanes, Building Blocks, C9 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Organic Building Blocks, Oxygen Compounds
  • {SNA} Alcohols, Benzodioxanes, Building Blocks, C9 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • FT-IR 1 (1), 1148:D / FT-IR 2 (2), 1957:B / FT-NMR 1 (2), 377:C / IR-Spectra (2), 614:F / IR-Spectra (3), 692:E / NMR-Reference 2 (1), 960:C / RegBook 1 (1), 1337:H / Structure Index 1 , 206:A:4

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSF3660000
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#07246

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • Acros Organics:2-羟甲基-1,4-苯并二恶烷 2-Hydroxymethyl-1,4-benzodioxan, 98%(3663-82-9)
  • Sigma Aldrich:3663-82-9(sigmaaldrich)
  • TCI Shanghai:2-羟甲基-1,4-苯并二恶烷 2-Hydroxymethyl-1,4-benzodioxane,>;98.0%(GC)(3663-82-9)
  • 2-羟基甲基-1,4-苯二恶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0801 2-羟甲基-1,4-苯并二恶烷 2-Hydroxymethyl-1,4-benzodioxane 500G 5090元 2014/06/02 H0801 2-羟甲基-1,4-苯并二恶烷 2-Hydroxymethyl-1,4-benzodioxane 25G 615元 2010/06/21 121410250 2-羟基甲基-1,4-苯二恶 2-Hydroxymethyl-1,4-benzodioxan 98% 25 GR 1065元
  • Alfa Aesar:2-羟基甲基-1,4-苯并二烷,98% 2-Hydroxymethyl-1,4-benzodioxane, 98%(3663-82-9)
  • 2-羟基甲基-1,4-苯二恶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 H0801 2-羟甲基-1,4-苯并二恶烷 2-Hydroxymethyl-1,4-benzodioxane 500G 5970元 2011/04/16 H0801 2-羟甲基-1,4-苯并二恶烷 2-Hydroxymethyl-1,4-benzodioxane 25G 721元 2010/06/21 121410250 2-羟基甲基-1,4-苯二恶 2-Hydroxymethyl-1,4-benzodioxan 98% 25 GR 1065元
  • 下游产品:2-羟甲基-1,4-苯并二噁烷对甲苯磺酸酯
  • 方法一:用邻苯二酚与环氧氯丙烷在氢氧化钾参与下环合制得。
  • 上游原料:环氧氯丙烷 --> 邻苯二酚
  • 用途一:胍生硫酸盐的中间体。
  • MOL 文件:3663-82-9.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Benzodioxanes 苯并二恶烷
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  6. C9 to C10 - Alcohols

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