1-Bromo-2-nitrobenze 1-溴-2-硝基苯

CAS 577-19-5 MFCD00007045

化学结构图

577-19-5
SMILES: O=[N+]([O-])c1ccccc1Br

化学属性

Mol. FormulaC6H4BrNO2
Mol. Weight202
Boiling Point264°C(lit.)
Melting Point40.0 to 43.0 deg-C
Density1.719
Flash Point112°(233°F)
TSCAYes
Solubility不溶于水，溶于乙醇、乙醚、丙酮、苯等多数有机溶剂。

别名和识别编码

Chemical Name1-Bromo-2-nitrobenze
CAS Number577-19-5
PubChem Substance ID11341
EC Number209-409-0
Beilstein Registry Number5(1)247
MDL NumberMFCD00007045
Reaxys-RN2044109
Synonym 1-Bromo-2-nitrobenzene {LY} 1-Bromo-2-nitrobenzene 1-bromo-2-nitro-benzen 1-bromo-2-nitro-benzene 1-溴-2-硝基苯 1-溴-2-硝基苯,99% 1-溴-2-硝基苯; 邻硝基溴苯; 2-溴硝基苯 1-溴代-2-硝基苯 2-BROMONITROBENZENE 2-Brom-nitrobenzol 2-Bromnitrobenzol 2-Bromo-1-nitrobenzene 2-Bromo-nitrobenzene 2-Bromonitrobenzene 2-Bromonitrobenzene2-Nitrobromobenzene 2-Nitrobromobenzene 2-Nitrophenyl bromide 2-溴-1-硝基苯 2-溴硝基苯 2-硝基溴苯 3-bromonitrobenzene o-Bromnitrobenzol o-Bromonitrobenzene o-Nitrobromobenzene {} {LY} 1-Bromo-2-nitrobenzene {} {} {LY} 1-Bromo-2-nitrobenzene {} {} {} {LY} 1-Bromo-2-nitrobenzene {} {} {} {} {} {} {} {} {LY} 1-Bromo-2-nitrobenzene {} {} {} {} {} {LY} 1-Bromo-2-nitrobenzene {} {} {
Chemical Name Translation1-溴-2-硝基苯
InChIKeyORPVVAKYSXQCJI-UHFFFAOYSA-N
LabNetwork Molecule IDLN00195054
InChIInChI=1S/C6H4BrNO2/c7-5-3-1-2-4-6(5)8(9)10/h1-4H
Canonical SMILESBrC1=CC=CC=C1[N+]([O-])=O
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分类

  • {SA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks
  • Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: II/25D
  • Beilstein:5(1)247
  • Short: II/27B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
RTECSCY9040450
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P301+P316
  • P301+P317
  • P302+P352
  • P302+P352+P312+P361+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P317
  • P361+P364
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
UN Number UN3459 3459
Packing GroupIII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 250 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

Restrict 危险品

其他信息

  • 上游原料:溴化亚铜 --> 2-硝基苯胺 --> 淀粉-碘化钾试纸
  • 1-溴-2-硝基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0622 2-溴硝基苯 2-Bromonitrobenzene 25G 439元 2014/06/02 B0622 2-溴硝基苯 2-Bromonitrobenzene 500G 4330元 2010/06/21 150351000 1-溴-2-硝基苯 1-Bromo-2-nitrobenzene 98% 100 GR 8486元
  • Alfa Aesar:1-溴-2-硝基苯,99% 1-Bromo-2-nitrobenzene, 99%(577-19-5)
  • 方法一:由邻硝基苯胺经下列步骤制得。将邻硝基苯胺和硫酸的混合物冷却至0-5℃，在搅拌下慢慢加入亚硝酸钠水溶液，至反应对淀粉碘化钾试纸变蓝。将所得的重氮盐溶液在搅拌下慢慢加入40℃的溴化亚铜溶液中。冷却后用乙醚提取，提取液用碱液、盐酸溶液及水洗涤，回收乙醚后即得产品。产率约70%。
  • 图谱信息:1-溴-2-硝基苯(577-19-5)核磁图( 1 HNMR) 1-溴-2-硝基苯(577-19-5)红外图谱(IR3) 1-溴-2-硝基苯(577-19-5)核磁图( 13 CNMR) 1-溴-2-硝基苯(577-19-5)红外图谱(IR1) 1-溴-2-硝基苯(577-19-5)质谱(MS) 1-溴-2-硝基苯(577-19-5)红外图谱(IR2)
  • Sigma Aldrich:577-19-5(sigmaaldrich)
  • MOL 文件:577-19-5.mol
  • 用途一:有机合成中间体。
  • 可燃性危险特性:明火可燃; 高热放出有毒溴化物、氮氧化物气体
  • Hazard Note:Irritant
  • TCI Shanghai:1-溴-2-硝基苯 2-Bromonitrobenzene,>;99.0%(GC)(577-19-5)
  • 海关编码:29049085
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 灭火剂:雾状水、泡沫、二氧化碳、砂土
  • 外观性质:黄色结晶。
  • Acros Organics:1-溴-2-硝基苯 1-Bromo-2-nitrobenzene, 98%(577-19-5)
  • MSDS 信息:2-硝基溴苯(577-19-5).msds
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Isocyanides
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂