1-Fluoro-2-nitrobenzene 1-氟-2-硝基苯

CAS 1493-27-2 MFCD00007048

化学结构图

1493-27-2
SMILES: O=[N+]([O-])c1ccccc1F

化学属性

Refractive index1.5300 to 1.5340
TSCAYes
Solubilityimmiscible
Mol. FormulaC6H4FNO2
Mol. Weight141.10
Density1.338
Flash Point94°C
Appearance colorless liq.
Boiling Point228.9°C at 760 mmHg
Melting Point-9--6°C

别名和识别编码

Chemical Name1-Fluoro-2-nitrobenzene
EC Number216-088-0
Beilstein Registry Number607262
Synonym 1-Fluoro-2-nitrobenzene {LY} 1-Fluoro-2-nitrobenzene {} {LY} 1-Fluoro-2-nitrobenzene {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Fluoro-2-nitrobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID73895
Chemical Name Translation1-氟-2-硝基苯
Reaxys-RN607262
InChIKeyPWKNBLFSJAVFAB-UHFFFAOYSA-N
LabNetwork Molecule IDLN00225105
InChIInChI=1S/C6H4FNO2/c7-5-3-1-2-4-6(5)8(9)10/h1-4H
MDL NumberMFCD00007048
CAS Number1493-27-2
Canonical SMILESO=[N+](C1=CC=CC=C1F)[O-]
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分类

  • {SNA} Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

产品应用

  • 农药、医药及染料中间体。

相关文献及参考

  • The activating effect of aryl halides by o- or p-nitro groups is most pronounced for aryl fluorides, e.g. reacts readily with arylamines in a convenient synthesis of 2-nitrodiarylamines: Synthesis, 215 (1980).
  • Beilstein:5,241

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H310 Fatal in contact with skin 皮肤接触致命
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P301+P316
  • P302+P350
  • P302+P352
  • P302+P352+P312+P361+P364
  • P304+P340
  • P304+P340+P311
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupIII
UN Number 2810 UN2810
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes Xi,T,Xn Xi
Hazard Class6.1
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • color:deep greenish-yellow
  • 1-氟-2-硝基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0104 2-氟硝基苯 2-Fluoronitrobenzene 25G 288元 2014/06/02 F0104 2-氟硝基苯 2-Fluoronitrobenzene 500G 2160元 2010/06/21 119480500 1-氟-2-硝基苯 1-Fluoro-2-nitrobenzene 99% 50 ML 907元
  • MSDS 信息:1-Fluoro-2-nitrobenzene(1493-27-2).msds
  • 用途二:农药、医药及染料中间体。
  • TCI Shanghai:2-氟硝基苯 2-Fluoronitrobenzene,>;98.0%(GC)(1493-27-2)
  • Acros Organics:2-氟硝基苯 1-Fluoro-2-nitrobenzene, 99%(1493-27-2)
  • 上游原料:邻氯硝基苯
  • 不和水混溶。
  • 下游产品:4-（2-酮酸-1-苯并咪唑）哌啶 --> 7-氟吲哚 --> 4-氨基-3-氟苯酚
  • Sigma Aldrich:1493-27-2(sigmaaldrich)
  • Hazard Note:Toxic/Irritant
  • 海关编码:29049085
  • MOL 文件:1493-27-2.mol
  • 用途一:用作农药、医药及染料中间体
  • 检测方法:GC,NMR
  • 图谱信息:1-氟-2-硝基苯(1493-27-2)质谱(MS) 1-氟-2-硝基苯(1493-27-2)核磁图( 13 CNMR) 1-氟-2-硝基苯(1493-27-2)核磁图( 1 HNMR) 1-氟-2-硝基苯(1493-27-2)红外图谱(IR1) 1-氟-2-硝基苯(1493-27-2)Raman光谱
  • Alfa Aesar:1-氟-2-硝基苯,99% 1-Fluoro-2-nitrobenzene, 99%(1493-27-2)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Isocyanides
  1. Organo Fluorine
  2. Fluorine

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