4-Fluoro-3-Nitrobenzotrifluoride 2-硝基-4-三氟甲基氟苯

CAS 367-86-2 MFCD00007059

化学结构图

367-86-2
SMILES: O=[N+]([O-])c1cc(C(F)(F)F)ccc1F

化学属性

Mol. FormulaC7H3F4NO2
Mol. Weight209
Refractive index1.4600 to 1.4640
Boiling Point208°C/262mmHg(lit.)
Density1.494
Flash Point33°C(lit.)
TSCANo
Appearance 淡黄色透明液体，相对密度1.494，沸点92℃（15mmHg），折光率1.4620。

别名和识别编码

Chemical Name4-Fluoro-3-Nitrobenzotrifluoride
CAS Number367-86-2
Alfabeta NameFLUORONITROBENZOTRIFLUORIDE 43---
MDL NumberMFCD00007059
Synonym 4-氟-3-硝基三氟甲苯 4-Trifluoromethyl-2-nitro-1-fluorobenzene FNBT TIMTEC-BB SBB009902 4-Fluoro-3-nitrobenzofluoride 3-NITRO-4-FLUOROBENZOTRIFLUORIDE 4,ALPHA,ALPHA,ALPHA-TETRAFLUORO-3-NITROTOLUENE 4,α,α,α-四氟-3-硝基甲苯 2-硝基-4-三氟甲基氟苯 1-FLUORO-2-NITRO-4-(TRIFLUOROMETHYL)BENZENE 3-硝基-α,α,α,4-四氟甲苯 4,α,α,α-四氟-3-硝基甲苯 FNBT 1-Fluoro-2-nitro-4-(trifluoromethyl)benzene, 3-Nitro-α,α,α-4-tetrafluorotoluene 4-FLUORO-3-NITRO BENZOTRIFUORIDE 4-FLUORO-3-NITROTRIFLUOROMETHYLBENZENE 4,α,α,α-Tetrafluoro-3-nitrotoluene 3-Nitro-α,α,α,4-tetrafluorotoluene, 4,α,α,α-Tetrafluoro-3-nitroto 3-硝基-α,α,α,4-四氟甲苯 3-Nitro-4-Fluorobenzotrifluoride; 1-Fluoro-2-nitro-4-(trifluoromethyl)-benzene 2-Fl
PubChem Substance ID87570097
EC Number206-702-5
Beilstein Registry Number5(4)853
Reaxys-RN1880508
Chemical Name Translation2-硝基-4-三氟甲基氟苯
InChIKeyHLDFCCHSOZWKAA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00175383
InChIInChI=1S/C7H3F4NO2/c8-5-2-1-4(7(9,10)11)3-6(5)12(13)14/h1-3H
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Fluorinated Building Blocks, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks, Organic Fluorinated Building Blocks, Trifluoromethyl

相关文献及参考

  • Beilstein:5(4)853
  • The nitro-group can be selectively displaced with KF in sulfolane, in the presence of phthaloyl chloride as a nitrite trap: J. Org. Chem., 56, 6406 (1991).

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Packing GroupIII
UN Number 1993 UN2810
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Hazard Codes
Hazard Class3
Storage condition Flammables area

其他信息

  • 图谱信息:2-硝基-4-三氟甲基氟苯(367-86-2)质谱(MS) 2-硝基-4-三氟甲基氟苯(367-86-2)核磁图( 1 HNMR) 2-硝基-4-三氟甲基氟苯(367-86-2)红外图谱(IR1) 2-硝基-4-三氟甲基氟苯(367-86-2)核磁图( 13 CNMR)
  • color:deep greenish-yellow
  • Hazard Note:Flammable/Irritant
  • TCI Shanghai:4-氟-3-硝基三氟甲苯 4-Fluoro-3-nitrobenzotrifluoride,>;95.0%(GC)(367-86-2)
  • 2-硝基-4-三氟甲基氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 TF032401 4-氟-3-硝基三氟甲苯 25g 360元 2011/04/16 F0324 4-氟-3-硝基三氟甲苯 4-Fluoro-3-nitrobenzotrifluoride 25G 333元 2011/04/16 F0324 4-氟-3-硝基三氟甲苯 4-Fluoro-3-nitrobenzotrifluoride 250G 1710元
  • Acros Organics:4-氟-3-硝基三氟甲苯 4-Fluoro-3-nitrobenzotrifluoride, 96%(367-86-2)
  • Alfa Aesar:4-氟-3-硝基三氟甲苯,97% 4-Fluoro-3-nitrobenzotrifluoride, 97%(367-86-2)
  • MOL 文件:367-86-2.mol
  • Sigma Aldrich:367-86-2(sigmaaldrich)
  • 检测方法:GC,NMR
  • MSDS 信息:3-Nitro-4-Fluorobenzotrifluoride(367-86-2).msds

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents HPLC - Derivatization Reagents
  5. UV-VIS - Derivatization Reagents HPLC
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Isocyanides