2-Nitroanisole 2-硝基苯甲醚

CAS 91-23-6 MFCD00007096

化学结构图

91-23-6
SMILES: COc1ccccc1[N+](=O)[O-]

化学属性

Mol. FormulaC₇H₇NO₃
Mol. Weight153.14
Refractive index1.5590 to 1.5630
Boiling Point-
Density1.254 g/mL at 25 °C(lit.)
Melting Point9-12 °C(lit.)
Flash Point-
TSCAYes
Solubility1.45 G/L (20 ºC)

别名和识别编码

Chemical Name2-Nitroanisole
MDL Number-
CAS Number91-23-6
Synonym 1-METHOXY-2-NITROBENZENE 1-Methoxy-2-nitrobenzene 1-Methoxy-2-nitrobenzol 1-Nitro-2-methoxybenzene 1-methoxy-2-nitro-benzen 1-methoxy-2-nitro-benzene 1-甲氧基-2-硝基苯 2-METHOXYNITROBENZENE 2-Methoxy-1-nitrobenzene 2-Methoxynitrobenzene 2-NITRO-ANISOLE 2-NITROANISOL 2-NITROANISOL OEKANAL, 250 MG 2-NITROANISOLE 2-NITROANISOLE, 99+% 2-Nitroanisole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87573512
EC Number202-052-1
Beilstein Registry Number6,217
Merck Number6584
Chemical Name Translation2-硝基苯甲醚
Reaxys-RN1868032
Wiswesser Line NotationWNR BO1
LabNetwork Molecule IDLN00220774
InChIInChI=1S/C7H7NO3/c1-11-7-5-3-2-4-6(7)8(9)10/h2-5H,1H3
Canonical SMILES-
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信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ether; 1fragment

产品应用

  • 生化研究。染料中间体。

相关文献及参考

  • Short: III/35D2
  • Merck: 14,6585 Beilstein:6,217
  • Short: II/27B
  • Short: II/5
  • Merck: 14,6585

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H350 May cause cancer 可能致癌
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSBZ8790000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P308+P313
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupIII
UN Number 2730 UN 2730 6.1/PG 3 UN2730
Risk Statements
  • R45 May cause cancer 可能致癌
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Hazard Codes T
Storage condition +4 4 4°C, Inert atmosphere 密封阴凉保存。
Hazard Class6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 9604 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - leukemia
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-416,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 173 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-416,1993

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 740 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(1),85,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1300 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(1),85,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 1060 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 500 nL/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,11,1986

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 123 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 666 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

Restrict 危险品

其他信息

  • MSDS 信息:2-硝基苯甲醚(91-23-6).msds
  • TCI Shanghai:2-硝基苯甲醚 2-Nitroanisole,>;98.0%(GC)(91-23-6)
  • 用途一:该品用于染料、医药、香料等工业，可用来制造邻氨基苯甲醚、联大茴香胺、色酚AS-OL、大红色基B、直接湖蓝6B、活性溶蓝KD-7G、净洗剂LS等。
  • 毒性分级:中毒
  • 类别:有毒物品
  • 2-硝基苯甲醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0125 2-硝基苯甲醚 2-Nitroanisole 500G 390元 2014/06/02 N0125 2-硝基苯甲醚 2-Nitroanisole 25G 104元 2010/05/25 A19518 2-硝基苯甲醚, 99% 2-Nitroanisole, 99% 500g 344元
  • 上游原料:氢氧化钠 --> 甲醇 --> 甲醇钠 --> 邻氯硝基苯
  • Sigma Aldrich:91-23-6(sigmaaldrich)
  • MOL 文件:91-23-6.mol
  • 急性毒性:口服-大鼠LD50: 740 毫克/公斤; 口服-小鼠 LD50: 1300 毫克/公斤
  • 图谱信息:2-硝基苯甲醚(91-23-6)质谱(MS) 2-硝基苯甲醚(91-23-6)核磁图( 13 CNMR) 2-硝基苯甲醚(91-23-6)Raman光谱 2-硝基苯甲醚(91-23-6)红外图谱(IR1) 2-硝基苯甲醚(91-23-6)红外图谱(IR2)
  • 方法一:邻硝基氯苯和烧碱、甲醇进行甲氧基化反应得粗品，粗品经蒸馏、洗涤、干燥，得成品。原料消耗定额：邻硝基氯苯1120kg/t、甲醇270kg/t。
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 职业标准:STEL 1 毫克/立方米
  • 外观性质:无色结晶或微红色液体。
  • Alfa Aesar:2-硝基苯甲醚,99% 2-Nitroanisole, 99%(91-23-6)
  • 海关编码:29093090
  • Acros Organics:2-硝基苯甲醚 2-Nitroanisole, 99+%(91-23-6)
  • 能随水蒸气挥发。溶于乙醇、乙醚、氯仿和二噁烷，水中溶解度:1.45 g/l (20°C)。有毒。
  • 可燃性危险特性:遇明火可燃; 燃烧产生有毒氮氧化物烟雾
  • 灭火剂:二氧化碳、泡沫、砂土、雾状水

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds

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