2,6-Dibromo-4-Nitrophenol 2,6-二溴-4-硝基苯酚

CAS 99-28-5 MFCD00007334

化学结构图

99-28-5
SMILES: O=[N+]([O-])c1cc(Br)c(O)c(Br)c1

化学属性

Mol. FormulaC6H3Br2NO3
Mol. Weight296.90
Melting Point145 °C
TSCAYes
Appearance 黄色柱状结晶。熔点144℃，在144℃以上分解。溶于醚、二硫化碳、乙酸乙酯、氯仿和热醇，难溶于苯、乙酸和石油醚，几乎不溶于水。能随水蒸汽挥发。
Boiling Point297.8±40.0 °C at 760 mmHg

别名和识别编码

Chemical Name2,6-Dibromo-4-Nitrophenol
MDL NumberMFCD00007334
PubChem Substance ID7429
CAS Number99-28-5
EC Number202-744-3
Reaxys-RN1245050
Beilstein Registry Number6(4)1366
Synonym 2,6-Dibromo-4-nitrophenol {LY} 2,6-Dibromo-4-nitrophenol {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-nitrophenol {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation2,6-二溴-4-硝基苯酚
InChIKeyWBHYZUAQCSHXCT-UHFFFAOYSA-N
Wiswesser Line NotationWNR DQ CE EE
LabNetwork Molecule IDLN01110980
InChIInChI=1S/C6H3Br2NO3/c7-4-1-3(9(11)12)2-5(8)6(4)10/h1-2,10H
Canonical SMILESOC1=C(Br)C=C([N+]([O-])=O)C=C1Br
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分类

  • Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

相关文献及参考

  • Beil. 6 ,247
  • FT-IR 2 (2), 2324:B / FT-NMR 1 (2), 762:B / IR-Spectra (3), 832:E / IR-Spectra (2), 729:D / RegBook 1 (1), 1593:M / Structure Index 1 , 248:D:6 / Vapor Phase 3 , 1216:B
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of structural parameters in structural formula by using different theoretical methods available in the literature.
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P332+P313
  • P302+P352+P312+P362+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
Hazard statements
  • H302+H312+H332
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn Xn,C
RTECSSK8025000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03498

Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • TCI Shanghai:2,6-二溴-4-硝基苯酚 2,6-Dibromo-4-nitrophenol,>;95.0%(T)(99-28-5)
  • Sigma Aldrich:99-28-5(sigmaaldrich)
  • MOL 文件:99-28-5.mol
  • 用途一:作有机合成的中间体。
  • Alfa Aesar:2,6-二溴-4-硝基苯酚,98% 2,6-Dibromo-4-nitrophenol, 98%(99-28-5)
  • 图谱信息:2,6-二溴-4-硝基苯酚(99-28-5)质谱(MS) 2,6-二溴-4-硝基苯酚(99-28-5)红外图谱(IR1) 2,6-二溴-4-硝基苯酚(99-28-5)Raman光谱 2,6-二溴-4-硝基苯酚(99-28-5)核磁图( 13 CNMR) 2,6-二溴-4-硝基苯酚(99-28-5)红外图谱(IR2) 2,6-二溴-4-硝基苯酚(99-28-5)核磁图( 1 HNMR)
  • 方法一:由对硝基酚经溴化而得。对硝基酚与冰醋酸混合后搅拌，使之全部溶解，在20-25℃慢慢加入溴和冰醋酸的混合溶液，约3h加完，加毕搅拌1h，在85℃保温1h。通压缩合赶去溴，加水搅拌析出沉淀，冷却6h，过滤，用50%乙酸洗涤结晶，然后用水洗，在40-60℃下干燥得粗品。再用乙酸重结晶而得成品。
  • 2,6-二溴-4-硝基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0197 2,6-二溴-4-硝基苯酚 2,6-Dibromo-4-nitrophenol 25G 513元 2010/05/25 A12916 2,6-二溴-4-硝基苯酚, 98% 2,6-Dibromo-4-nitrophenol, 98% 25g 410元 2010/05/25 A12916 2,6-二溴-4-硝基苯酚, 98% 2,6-Dibromo-4-nitrophenol, 98% 250g 2800元
  • 上游原料:4-硝基苯酚

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C6 to C8 - Phenols

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