(Tert-Butoxycarbonylmethyl)Triphenylphosphanium Bromide (叔丁氧基羰基甲基)三苯基溴化磷

CAS 59159-39-6 MFCD00075527

化学结构图

59159-39-6
SMILES: [Br-].CC(C)(C)OC(=O)C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC24H26BrO2P
Mol. Weight457
Melting Point178
TSCANo

别名和识别编码

Chemical Name(Tert-Butoxycarbonylmethyl)Triphenylphosphanium Bromide
Synonym Carbo-tert-butoxymethyl triphenylphosphonium bromide NSC 82468 (叔丁氧基羰基甲基)溴化三苯基磷
MDL NumberMFCD00075527
PubChem Substance ID135727355
CAS Number59159-39-6
Beilstein Registry Number4631405
Chemical Name Translation(叔丁氧基羰基甲基)三苯基溴化磷
LabNetwork Molecule IDLN00223787
Reaxys-RN4631405
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Huang, Y.; et al. Adv. Synth. Catal. 351 , 1423, (2009)
  • 2. Prasada Raju, V. V. N. K. V.; et al. Org. Process Res. Dev. 13 , 710, (2009)
  • 3. Nishimoto, Y.; et al. J. Org. Chem. 73 , 9465, (2008)
  • 4. Cabral dos Santos, L.; et al. Heterocycles 73 , 751, (2007)
  • 5. Suzuki, Y.; Sato, M. Tetrahedron Lett. 45 , 1679, (2004)
  • 6. Railton, C. J.; Clive, Derrick L. J. Carbohydr. Res. 281 , 69, (1996)
  • FT-NMR 1 (2), 1678:B / RegBook 1 (2), 2279:E / Structure Index 1 , 357:B:1

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination

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