2-Fluoroaniline 邻氟苯胺
CAS 348-54-9 MFCD00007642
化学结构图
SMILES: Nc1ccccc1F
化学属性
| Mol. Formula | C₆H₆FN |
|---|---|
| Mol. Weight | 111.12 |
| Density | 1.151 |
| Refractive index | 1.5400 to 1.5430 |
| Boiling Point | |
| Melting Point | No Data Available |
| Flash Point | 60°C |
| TSCA | Yes |
| Solubility | 不溶于水，溶于乙醇、乙醚。 |
| Stability | 对光线、空气敏感 |
| pH | :A |
别名和识别编码
| Chemical Name | 2-Fluoroaniline |
|---|---|
| Synonym | 2-Fluoroaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| MDL Number | MFCD00007642 |
| CAS Number | 348-54-9 |
| EC Number | 206-478-9 |
| Beilstein Registry Number | 1524219 |
| PubChem Substance ID | 9584 |
| Reaxys-RN | 1524219 |
| Chemical Name Translation | 邻氟苯胺 |
| InChIKey | FTZQXOJYPFINKJ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00226508 |
| InChI | InChI=1S/C6H6FN/c7-5-3-1-2-4-6(5)8/h1-4H,8H2 |
| Canonical SMILES | NC1=CC=CC=C1F |
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分类
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
相关文献及参考
- Short: II/25D
- Short: II/14a
- Short: II/19b
- Beilstein:12(1)296
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S39 Wear eye/face protection 戴眼睛/面孔保护装置；
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R33 Danger of cumulative effects 有累积作用的危险
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P337+P313
- P403+P233
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P312+P361+P364
- P303+P361+P353
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P304+P340+P311
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P305+P351+P338+P337+P313
- P241+P242+P243
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H318 Causes serious eye damage 严重伤害眼睛
- H302 Harmful if swallowed 吞食有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- 海关编码:29214210
- An intermediate in the synthesis of Flurbiprofen.
- MOL 文件:348-54-9.mol
- Acros Organics:2-氟苯胺 2-Fluoroaniline, 99+%(348-54-9)
- Hazard Note:Toxic/Irritant
- TSCA:T
- MSDS 信息:邻氟苯胺(348-54-9).msds
- Alfa Aesar:2-氟苯胺,99% 2-Fluoroaniline, 99%(348-54-9)
- 检测方法:GC,NMR
- 图谱信息:2-氟苯胺(348-54-9)核磁图( 13 CNMR) 2-氟苯胺(348-54-9)质谱(MS) 2-氟苯胺(348-54-9)红外图谱(IR1)
- 外观性质:淡黄色液体。
- 邻氟苯胺:邻氟苯胺是一种无色至淡黄色透明液体，有毒，不溶于水，溶于乙醇、乙醚，可用作分析试剂，对皮肤有刺激作用，蒸气或烟雾对眼睛、粘膜和上呼吸道有刺激作用，进入人体内，可形成高铁血红蛋白致紫绀。其蒸气与空气可形成爆炸性混合物，遇明火、高热能引起燃烧爆炸。与氧化剂可发生反应。受高热分解放出有毒的气体。若遇高热，容器内压增大，有开裂和爆炸的危险。
- TCI Shanghai:2-氟苯胺 2-Fluoroaniline,>;99.0%(GC)(348-54-9)
- 2-氟苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0032 2-氟苯胺 2-Fluoroaniline 25G 206元 2014/06/02 F0032 2-氟苯胺 2-Fluoroaniline 500G 1520元 2010/06/21 119275000 2-氟苯胺 2-Fluoroaniline 99+% 500 ML 2414元
- Sigma Aldrich:348-54-9(sigmaaldrich)
- 水中溶解度:17 g/L (20°C)，溶于四氯化碳、乙醚和乙醇。
- 下游产品:氟虫脲 --> 三唑酮草酯 --> 4-溴-2-氟苯腈 --> 1-(2-氟苯基)哌嗪盐酸盐 --> 2-氟苯基异氰酸酯
- 上游原料:氢 --> 邻氯硝基苯 --> 氟化钾 --> 2-氟丙酸乙酯
- 用途一:用作医药、农药及染料中间体
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